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Perkin Transactions 1 1972-2002 logo

Year 1997
Main Index

Issue 1



Patrick D Cunningham Niall W. A. Geraghty Patrick J. McArdle Paul V. Murphy and Timothy J. O'Sullivan
pg 1; DOI:
10.1039/a604850a
PDF
Synthesis of 1,2,4-trioxanes and 1,2,4-trioxepanes by N-halogenosuccinimide-mediated cyclisations of unsaturated hydroperoxyacetals
Yoshihiro Ushigoe Yoshihiro Kano and Masatomo Nojima
pg 5; DOI:
10.1039/a605616d
PDF
2-Halogeno-1,3-dithiane 1,3-dioxide: a diastereoselective carbonyl anion equivalent in reactions with aldehydes
Varinder K. Aggarwal Giorgio Boccardo Julia M. Worrall Harry Adams and Rikki Alexander
pg 11; DOI:
10.1039/a603416k
PDF
Direct measurement of the anomeric effect in sulfoxides: conformational analysis and X-ray crystal structures of 2-bromo- and 2-chloro-1,3-dithiane trans-1,3-dioxides
Varinder K. Aggarwal Julia M. Worrall Harry Adams Rikki Alexander and Brian F. Taylor
pg 21; DOI:
10.1039/a605535d
PDF
Generation and reaction of benzylammonium N-methylides with N-cyanomethyl or N-(ethoxycarbonylalkyl) groups
Chen Zhang Yasuhiro Maeda Naohiro Shirai and Yoshiro Sato
pg 25; DOI:
10.1039/a605337h
PDF

Masataka Yokoyama Hirofumi Toyoshima Miyuki Shimizu and Hideo Togo
pg 29; DOI:
10.1039/a604474c
PDF
Preparation of new 2,4-disubstituted oxazoles from N-acylaziridines
Frank W. Eastwood Patrick Perlmutter and Qi Yang
pg 35; DOI:
10.1039/a604091h
PDF
Studies on the role of conformation and of hydrogen-bonding on the dihydroxylation of cyclic allylic alcohols: application to the synthesis of conduritol D
Timothy J. Donohoe Peter R. Moore and Roy L. Beddoes
pg 43; DOI:
10.1039/a604052g
PDF
Synthetic approaches toward ecteinascidins. Part 1. Preparation of an (E)-2-arylidene-3-benzyl-1,5-imino-3-benzazocin-4-one having a protected phenol in the E-ring
Naoki Saito Kyoichi Tashiro Yukie Maru Kentaro Yamaguchi and Akinori Kubo
pg 53; DOI:
10.1039/a603292c
PDF
Stereoselective benzylic -acylamino radical cyclisation: a model study for the Tacaman indole alkaloid skeleton
Rainer Clauss and Roger Hunter
pg 71; DOI:
10.1039/a602932i
PDF
Intramolecular photo[4+2]cycloaddition of an enone with a benzene ring
Keiki Kishikawa Satoshi Akimoto Shigeo Kohmoto Makoto Yamamoto and Kazutoshi Yamada
pg 77; DOI:
10.1039/a601710j
PDF

Issue 2


Intramolecular Vilsmeier processes: a new route to cyclopenta[b]- and cyclohexa[b]-fused quinolines by cyclisation of adipic and pimelic bis-amides
Otto Meth-Cohn and Simon Goon
pg 85; DOI:
10.1039/a605294k
PDF
Preparation and structure–chiroptical relationships of tartaric acid-based layer-block chiral dendrimers
Hak-Fun Chow and Chi Ching Mak
pg 91; DOI:
10.1039/a604539a
PDF
Synthesis of sphingosine relatives. Part 19.1 Synthesis of penaresidin A and B, azetidine alkaloids with actomyosin ATPase-activating properties
Hirosato Takikawa Takeshi Maeda Masanori Seki Hiroyuki Koshino and Kenji Mori
pg 97; DOI:
10.1039/a604276g
PDF
Tandem Beckmann and Huisgen–White rearrangement of the 9-azabicyclo[3.3.1]nonan-3-one system. Part 2.1 The second mode of the rearrangement leading to 6-(prop-1-enyl)piperidin-2-ylacetic acid, a versatile intermediate for the syntheses of piperidine alkaloids (+)-pinidine and (+)-monomorine I
Osamu Muraoka Bao-Zhong Zheng Kazuhito Okumura Emi Tabata Genzoh Tanabe and Michinori Kubo
pg 113; DOI:
10.1039/a604266j
PDF
The phototransformation of 5-tert-butyl-2-deoxyuridine: an approach to the synthesis of new 1,2-dihydrocyclobuta[d]pyrimidin-2-ones1
Ivan Basnak Denise McKinnell Neil Spencer Ayla Balkan Peter R. Ashton and Richard T. Walker
pg 121; DOI:
10.1039/a604244i
PDF
Use of linker for preparation of missing solid-state photoproducts: head-to-head photodimerization of anthracene-9-propionic acid in its crystalline double salt with cyclohexane-1,2-diamine
Yoshikatsu Ito and Gunnar Olovsson
pg 127; DOI:
10.1039/a604176k
PDF
Reactions involving fluoride ion. Part 41.1,2 Synthesis of hexakis(trifluoromethyl)cyclopentadiene and derived cyclopentadienide salts
Richard D. Chambers William K. Gray Julian F. S. Vaughan Stewart R. Korn Maurice Médebielle Andrei S. Batsanov Christian W. Lehmann and Judith A. K. Howard
pg 135; DOI:
10.1039/a604087j
PDF
Stereoselective synthesis of (Z)--(alkoxycarbonyl)methylene - and -lactones by palladium-catalysed oxidative carbonylation of alkynols
Bartolo Gabriele Giuseppe Salerno Francesca De Pascali Mirco Costa and Gian Paolo Chiusoli
pg 147; DOI:
10.1039/a603892a
PDF
Use of highly stereospecific 1,3-dipolar cycloadditions of cyclic nitrones with acetylenes in the preparation of novel heterocyclic ring systems
W. Russell Bowman Roy V. Davies Alexandra M. Z. Slawin Gian S. Sohal Roger B. Titman and David J. Wilkins
pg 155; DOI:
10.1039/a602598f
PDF
Synthesis and reactions of reduced flavones
W. Groundwater E. Hibbs B. Hursthouse and Miklós Nyerges
pg 163; DOI:
10.1039/a602245f
PDF
Synthesis of alkylene linked bis-THA and alkylene linked benzyl-THA as highly potent and selective inhibitors and molecular probes of acetylcholinesterase
Yuan-Ping Pang Feng Hong Polly Quiram Tanya Jelacic and Stephen Brimijoin
pg 171; DOI:
10.1039/a601642a
PDF
Synthesis of chiral tricyclo[3.2.1.02,7]octanes by an efficient 3-exo-trig radical cyclisation reaction1
Adusumilli Srikrishna and G. Veera Raghava Sharma
pg 177; DOI:
10.1039/a601315e
PDF

Issue 3


Facilitation of displacements at the 6-position of purines by the use of 1,4-diazabicyclo[2.2.2]octane as leaving group
Nicola K. Lembicz Sharon Grant William Clegg Roger J. Griffin Sarah L. Heath and Bernard T. Golding
pg 185; DOI:
10.1039/a608207f
PDF
Structures of Us-7 and Us-8: a new type of oxindole alkaloids isolated from Uncaria attenuata Korth
Norio Aimi Toshikazu Shimizu Hiroyuki Sada Hiromitsu Takayama Shin-ichiro Sakai Sumphan Wongseripipatana and Dhavadee Ponglux
pg 187; DOI:
10.1039/a607017e
PDF
Facile construction of spirobicyclic skeletons by intramolecular aldol reaction: simple formal syntheses of ()-spirojatamol and ()-erythrodiene
Yuji Tokunaga Maki Yagihashi Masataka Ihara and Keiichiro Fukumoto
pg 189; DOI:
10.1039/a606151f
PDF
Facile preparation of acetals and enol ethers derived from 1-arylpiperidin-4-ones
Montserrat Faja Colin B. Reese Quanlai Song and Pei-Zhuo Zhang
pg 191; DOI:
10.1039/a606191e
PDF
Synthesis based on cyclohexadienes. Part 21.1 Total synthesis of ()-hinesol and ()-10-epi-hinesol
Seenivasaga N. Janaki and G. S. R. Subba Rao
pg 195; DOI:
10.1039/a606197d
PDF
Conversion of imino-1,2,3-dithiazoles into 2-cyanobenzothiazoles, cyanoimidoyl chlorides and diatomic sulfur
Russell F. English Oleg A. Rakitin Charles W. Rees and Olga G. Vlasova
pg 201; DOI:
10.1039/a605815i
PDF
A mild oxidative transformation of nitro compounds into ketones by tetrapropylammonium perruthenate
Yuji Tokunaga Masataka Ihara and Keiichiro Fukumoto
pg 207; DOI:
10.1039/a606332b
PDF
Regio- and stereo-selective additions of sodium selenides to conjugate enyne sulfones: a convenient synthesis of 4-seleno-1-sulfonylbuta-1,3-dienes
Mitsuhiro Yoshimatsu and Junko Hasegawa
pg 211; DOI:
10.1039/a605547h
PDF
Regioselective 1,4-addition of ammonia to 1-arylalka-1,3-dienes and 1-aryl-4-phenylbuta-1,3-dienes by photoinduced electron transfer
Ryuji Kojima Toshiaki Yamashita Kimiko Tanabe Tsutomu Shiragami Masahide Yasuda and Kensuke Shima
pg 217; DOI:
10.1039/a605465j
PDF
Cycloaddition vs. conjugative Michael-type addition of 2-ethoxy-3-morpholinobuta-1,3-diene with nitroolefins
Gaper Marc Patrizia Nitti Giuliana Pitacco Alessandro Pizzioli and Ennio Valentin
pg 223; DOI:
10.1039/a605345i
PDF
1,2-Dihydroquinolin-2-one (carbostyril) anions as bidentate nucleophiles in their reactions with aryllead triacetates: synthesis of 1-aryl- and 3-aryl-tetrahydroquinoline-2,5,8-triones
Pilar López-Alvarado Carmen Avendaño and J. Carlos Menéndez
pg 229; DOI:
10.1039/a605139a
PDF
Asymmetric reduction of 1-methylsulfonylalkan-2-ones with bakers yeast
Anita R. Maguire and Declan G. Lowney
pg 235; DOI:
10.1039/a605132d
PDF
Stable Cu+, Ag+ complexes of aza-bridged macrocyclic molecules: structure and chemical properties
Hiroyuki Takemura Noriyoshi Kon Keita Tani Kô Takehara Junko Kimoto Teruo Shinmyozu and Takahiko Inazu
pg 239; DOI:
10.1039/a604966d
PDF
Chemoselective N-deprotection of tert-butyl 2-(trifluoroacetylamino) esters under PTC conditions: synthesis of tert-butyl 2-aminocarboxylates
Domenico Albanese Francesco Corcella Dario Landini Angelamaria Maia and Michele Penso
pg 247; DOI:
10.1039/a604902h
PDF
Furan-fused 3-sulfolene as a novel building block: intermolecular Diels–Alder reactions of 4H,6H-thieno[3,4-c]furan 5,5-dioxide
Takayoshi Suzuki Kan Kubomura and Hiroaki Takayama
pg 251; DOI:
10.1039/a604600b
PDF
Acidity effect in the regiochemical control of the alkylation of phenol with alkenes
Giovanni Sartori Franca Bigi Raimondo Maggi and Attilio Arienti
pg 257; DOI:
10.1039/a604598g
PDF
Synthesis of chlorophyll a and -carotene from 2H- and 13C-labelled mevalonates and 13C-labelled glycine in cultured cells of liverworts, Heteroscyphus planus and Lophocolea heterophylla
Kensuke Nabeta Teruki Kawae Tatsuto Saitoh and Takahiro Kikuchi
pg 261; DOI:
10.1039/a604562f
PDF
A procedure for the preparation of cardioactive steroid precursors: synthesis of 3-acetoxy-21-hydroxy-5-pregn-14-en-20-one
Lumbu Simbi and Fanie R. van Heerden
pg 269; DOI:
10.1039/a604557j
PDF
Chiral and stereoselective total synthesis of (-)-mesembranol starting from D-glucose
Noritaka Chida Kohji Sugihara Seiji Amano and Seiichiro Ogawa
pg 275; DOI:
10.1039/a604365h
PDF
New solid-phase oligosaccharide synthesis on glycopeptides bound to a solid phase
Hans Paulsen Axel Schleyer Nathalie Mathieux Morten Meldal and Klaus Bock
pg 281; DOI:
10.1039/a604123j
PDF
New large cage receptors. An example of selective phloroglucinol binding
Ian M. Atkinson Anthony R. Carroll Ronald J. A. Janssen Leonard F. Lindoy Owen A. Matthews and George V. Meehan
pg 295; DOI:
10.1039/a604103e
PDF
Glyceryl-ether monooxygenase [EC 1.14.16.5]. Part 9. Stereospecificity of the oxygenase reaction
Hiroyasu Taguchi Bela Paal and Wilfred L. F. Armarego
pg 303; DOI:
10.1039/a603533g
PDF
Synthesis and reactions of lactam sulfonium salts with a sulfonio bridgehead. Part 1. 4,4a,5,6-Tetrahydro-5-oxo-1H-thiopyrano[1,2-a]-1,4-be nzothiazinium perchlorates
Tadashi Kataoka Yoshihide Nakamura Harutoshi Matsumoto Tetsuo Iwama Hirohito Kondo Hiroshi Shimizu Osamu Muraoka and Genzoh Tanabe
pg 309; DOI:
10.1039/a603348b
PDF
Total syntheses of (+)-asperlin, (+)-acetylphomalactone and (5S,6S,7R,8S)-asperlin based on the kinetic resolution of 2-furylmethanols
Zhi-Cai Yang Xiao-Bin Jiang Zhi-Min Wang and Wei-Shan Zhou
pg 317; DOI:
10.1039/a603209e
PDF
Episulfone substitution and ring-opening reactions via -sulfonyl carbanion intermediates
Allan P. Dishington Richard E. Douthwaite Andrew Mortlock Adriano B. Muccioli and Nigel S. Simpkins
pg 323; DOI:
10.1039/a602846b
PDF
Remote functionalization by tandem radical chain reactions
David Wiedenfeld
pg 339; DOI:
10.1039/a600172f
PDF

Issue 4


First total synthesis of carbazomycin C and D1
Hans-Joachim Knölker and Georg Schlechtingen
pg 349; DOI:
10.1039/a608351j
PDF
Preparation, structure, derivatisation and NMR data of cyclohexane-1,2-diacetal protected carbohydrates
Peter Grice Steven V. Ley Jörg Pietruszka Henning W. M. Priepke and Stuart L. Warriner
pg 351; DOI:
10.1039/a605851e
PDF
Synthesis of chiral intermediates of quinine alkaloids and (+)-dihydroantirhine
Masataka Ihara Nobuaki Taniguchi and Keiichiro Fukumoto
pg 365; DOI:
10.1039/a606952e
PDF
Total synthesis of milbemycin E: synthesis of the C(11)–C(25) fragment
Patrick G. Steel and Eric J. Thomas
pg 371; DOI:
10.1039/a605892b
PDF
Total synthesis of milbemycin E: development of a procedure for the introduction of the 3,4-double bond and synthesis of the C(1)–C(10) fragment
Emma R. Parmee Simon V. Mortlock Nicholas A. Stacey Eric J. Thomas and (the late) Owen S. Mills
pg 381; DOI:
10.1039/a605893k
PDF
Total synthesis of milbemycin E: resolution of the C(1)–C(10) fragment and final assembly
Patrick G. Steel (the late) Owen S. Mills Emma R. Parmee and Eric J. Thomas
pg 391; DOI:
10.1039/a605894i
PDF
Chiral base mediated asymmetric synthesis of tricarbonyl(6-arene)chromium complexes
Richard A. Ewin Angus M. MacLeod David A. Price Nigel S. Simpkins and Alan P. Watt
pg 401; DOI:
10.1039/a605812d
PDF
Asymmetric synthesis of 5,5-disubstituted thiotetronic acids using an allyl xanthate to dithiocarbonate rearrangement: total synthesis of (5S)-thiolactomycin with revision of the absolute configuration of the natural
Mark S. Chambers and Eric J. Thomas
pg 417; DOI:
10.1039/a605768c
PDF
Unusual reactions of methylsulfonyl esters: syntheses of 3-methyl and 3-methyl gibberellin A20
Michael H. Beale Huw Loaring Torren Peakman Martin Penny and Christine L. Willis
pg 433; DOI:
10.1039/a605570b
PDF
A simple method for the synthesis of 4-aryl-9-oxynaphthofuranone lignans
Kazuhiro Kobayashi Kouji Maeda Tomokazu Uneda Osamu Morikawa and Hisatoshi Konishi
pg 443; DOI:
10.1039/a605288f
PDF
Synthesis of conformationally constrained phenylalanine analogues via 7-, 8- and 9-endo Heck cyclisations
Susan E. Gibson (née Thomas) Nathalie Guillo Richard J. Middleton Audrey Thuilliez and Matthew J. Tozer
pg 447; DOI:
10.1039/a605286j
PDF
Diazo transfer reactions of tosyl azide with carbocyclic -keto esters: production and decomposition of ring-opened N-tosylcarbamoyl-substituted -diazo esters
Luisa Benati Daniele Nanni and Piero Spagnolo
pg 457; DOI:
10.1039/a605240a
PDF
Synthesis and NMR studies of key intermediates to a new class of -lactam: the trinems
Carla Marchioro Giorgio Pentassuglia Alcide Perboni and Daniele Donati
pg 463; DOI:
10.1039/a605081f
PDF
Fluoride ion-induced cyclization of o-[bis(trimethylsilyl)methyl]-N-acylbenzamide derivatives. New efficient synthesis of 2,3-differentially substituted 1(2H)-isoquinolones
Axel Couture Hélène Cornet Eric Deniau Pierre Grandclaudon and Stéphane Lebrun
pg 469; DOI:
10.1039/a605077h
PDF
Sequential and regioselective Friedel–Crafts reactions of gem-dihalogenocyclopropanecarbonyl chlorides with benzenes for the synthesis of 4-aryl-1-naphthol derivatives
Yoshinori Nishii and Yoo Tanabe
pg 477; DOI:
10.1039/a605030a
PDF
Reaction of 4-ethoxycarbonyl-2-phenyl-4,5-dihydrooxazol-5-one with organolead(IV) triacetates. A route to some -arylglycine and -vinylglycine derivatives
Mark J. Koen Jacqueline Morgan John T. Pinhey and Christopher J. Sherry
pg 487; DOI:
10.1039/a604899d
PDF
The synthesis of 3-phosphonocyclobutyl amino acid analogues of glutamic acid via diethyl 3-oxycyclobutylphosphonate, a versatile synthetic intermediate
Jane R. Hanrahan Paul C. Taylor and William Errington
pg 493; DOI:
10.1039/a604898f
PDF
An unexpected Mitsunobu reaction. A direct route to the 2,5-diazabicyclo[2.2.1]heptan-3-one skeleton as a -lactam mimic of -lactam antibiotics
Peter S. Hadfield Ron H. B. Galt Yvonne Sawyer Nicola J. Layland and Michael I. Page
pg 503; DOI:
10.1039/a604564b
PDF
Generation of homochiral aziridinium ion intermediates derived from 2,3-epoxy amines: regiospecific nucleophilic trapping with nitrogen nucleophiles. Application in the synthesis of novel morpholinosphingolipid analogues with potential glucosylceramide synthase inhibitory activity
Quanying Liu Allan P. Marchington Neville Boden and Christopher M. Rayner
pg 511; DOI:
10.1039/a604534k
PDF
Stereochemistry of the methoxide induced rearrangement of an -bromophosphonamidate: cleavage of the P–N and P–C bonds in the azaphosphiridine oxide intermediate1
Martin J. P. Harger and Ramesh Sreedharan-Menon
pg 527; DOI:
10.1039/a604093d
PDF
Lignin model glycosides: preparation and optical resolution
Richard F. Helm Merja Toikka Kaichang Li and Gösta Brunow
pg 533; DOI:
10.1039/a603786k
PDF
Amino acids bearing nucleobases for the synthesis of novel peptide nucleic acids
Gordon Lowe and Tirayut Vilaivan
pg 539; DOI:
10.1039/a603696a
PDF
Dipeptides bearing nucleobases for the synthesis of novel peptide nucleic acids
Gordon Lowe and Tirayut Vilaivan
pg 547; DOI:
10.1039/a603699f
PDF
Solid-phase synthesis of novel peptide nucleic acids
Gordon Lowe and Tirayut Vilaivan
pg 555; DOI:
10.1039/a603701a
PDF
Synthesis of bicyclo[4.1.0]hept-2-enes (trinorcarenes) by photochemical reaction of bicyclo[2.2.2]oct-5-en-2-ones
Sadamu Katayama Hajime Hiramatsu Keiichi Aoe and Masashige Yamauchi
pg 561; DOI:
10.1039/a601900e
PDF
Palladium-catalysed enantiodivergent synthesis of cis- and trans-4-aminocyclohex-2-enols
Roberto G. P. Gatti Anna L. E. Larsson and Jan-E. Bäckvall
pg 577; DOI:
10.1039/a600779a
PDF

Issue 5


New approach to p-hydroxybenzylation of arenes via a quinomethane generated in situ from a Mannich base
Woonphil Baik Hyun Joo Lee Chang Hyun Yoo Ji Won Jung and Byeong Hyo Kim
pg 587; DOI:
10.1039/a607418i
PDF
Stereoselective synthesis of ketene telluroacetals via hydrozirconation of acetylenic tellurides
Jin Wuk Sung Chan Pil Park Jun Mo Gil and Dong Young Oh
pg 591; DOI:
10.1039/a607232a
PDF
Additions of benzylsulfonium ylides to aldehydes and ketones: are they under kinetic or thermodynamic control?
Varinder K. Aggarwal Simone Calamai and J. Gair Ford
pg 593; DOI:
10.1039/a606925h
PDF
Synthesis and biological testing of pyrano[2,3-a]acridinones
Jacqueline A. Drewe and Paul W. Groundwater
pg 601; DOI:
10.1039/a606689e
PDF
Simple syntheses of L-fucopyranose and fucosidase inhibitors utilizing the highly stereoselective methylation of an arabinofuranoside 5-urose derivative
Shunya Takahashi and Hiroyoshi Kuzuhara
pg 607; DOI:
10.1039/a606564c
PDF
Reaction of organolead triacetates with 4-ethoxycarbonyl-2-methyl-4,5-dihydro-1,3-oxazol-5-one. The synthesis of -aryl- and -vinyl-N-acetylglycines and their ethyl esters and their enzymic resolution
Jacqueline Morgan John T. Pinhey and Christopher J. Sherry
pg 613; DOI:
10.1039/a606309h
PDF
2,2-Difluoro-1,3,2-oxazaborolidin-5-ones: novel approach for selective side-chain protection of serine and threonine
Jidong Wang Yoshio Okada Wei Li Toshio Yokoi and Jintao Zhu
pg 621; DOI:
10.1039/a606295d
PDF
Synthesis of (2R)-2-bromodehydroquinic acid and (2R)-2-fluorodehydroquinic acid
Michael K. Manthey Concepción González-Bello and Chris Abell
pg 625; DOI:
10.1039/a606104d
PDF
Nitrile oxide/isoxazoline approach to higher monosaccharides: synthesis of 7-deoxy-nonose and -decose derivatives1
R. Michael Paton and Anne A. Young
pg 629; DOI:
10.1039/a606093e
PDF
Facile access to 3-allyl- and 3-benzyl-3-cephems through reductive addition/cyclization of allenecarboxylate with allylic and benzylic halides in an [NiCl2(bipy)]/PbBr2/Al redox system
Hideo Tanaka Shin-ichi Sumida Kouichi Sorajo Yutaka Kameyama and Sigeru Torii
pg 637; DOI:
10.1039/a606049h
PDF
Nucleophilic introduction of fluorinated alkyl groups into aldehydes and ketones using the corresponding alkyl halide with samarium(II) iodide
Masato Yoshida Daiki Suzuki and Masahiko Iyoda
pg 643; DOI:
10.1039/a606048j
PDF
Preparation of N-substituted aspartic acids via enantiospecific conjugate addition of N-nucleophiles to fumaric acids using methylaspartase: synthetic utility and mechanistic implications1
M. Saeed Gulzar Mahmoud Akhtar and David Gani
pg 649; DOI:
10.1039/a605996a
PDF
Synthesis and inhibitory properties of (1R,2R,4R,6 R)-6-O -(2-hydroxyethyl)cyclohexane-1,2,4,6-tetraol derivatives: mechanistic probes for the inositol monophosphatase reaction1
Jürgen Schulz and David Gani
pg 657; DOI:
10.1039/a605998h
PDF
Mild, effective and regioselective ring-opening of oxiranes using several thiosilanes promoted by tetrabutylammonium fluoride as catalyst
Yoo Tanabe Kei Mori and Yoshihiro Yoshida
pg 671; DOI:
10.1039/a605964c
PDF
Pyrrolizidine alkaloid biosynthesis. Incorporation of 2-aminobutanoic acid labelled with 13C or 2H into the senecic acid portion of rosmarinine and senecionine
Iain R. Stirling Isabel K. A. Freer and David J. Robins
pg 677; DOI:
10.1039/a605623g
PDF
On the reaction of prop-2-enylidenetriphenylphosphorane derivatives. Novel synthesis of the azulene ring system
Tohru Takayasu and Makoto Nitta
pg 681; DOI:
10.1039/a605581h
PDF
Catalytic conjugate addition promoted by the copper(I)–monothiobinaphthol system. Part 2.1 Optimal ligand synthesis and initial catalytic results
Shamsudin M. Azad Simon M. W. Bennett Stephen M. Brown Jason Green Ekkehard Sinn Chris M. Topping and Simon Woodward
pg 687; DOI:
10.1039/a605620b
PDF
A convenient synthesis of alkynylpyrazoles
Mitsuhiro Yoshimatsu Masataka Kawahigashi Eiji Honda and Tadashi Kataoka
pg 695; DOI:
10.1039/a605542g
PDF
Unusual reactions in molecules with crowded functional groups: sulfonamide reduction under oxidizing conditions in camphor derivatives
Gabriele Wagner Rudolf Herrmann and Annette Schier
pg 701; DOI:
10.1039/a605472b
PDF
Synthesis of 1,4-di(n-pyridyl)buta-1,3-diyne and formation of charge-transfer complexes. X-Ray structure of 1,4-di(3-pyridyl)buta-1,3-diyne
J. Gonzalo Rodríguez Rosa Martín-Villamil Felix H. Cano and Isabel Fonseca
pg 709; DOI:
10.1039/a605468d
PDF
Synthesis of 3,4,6,7-tetrahydro-1H-5,2-benzoxathionines by S-ylide rearrangement
Tomoko Kitano Naohiro Shirai and Yoshiro Sato
pg 715; DOI:
10.1039/a605423d
PDF
Cyclisation studies of 5-arylalkyl-1,2,3,4,5,6,7,8-octahydroisoquinolines
Philip R. Dennison Alan Gibson Alexander I. Gray and Graham L. Patrick
pg 721; DOI:
10.1039/a605296g
PDF
Dendrimeric silatrane wedges
Tim Kemmitt and William Henderson
pg 729; DOI:
10.1039/a605135i
PDF
A new approach to 1-deoxy-azasugars: asymmetric synthesis of 1-deoxymannojirimycin and 1-deoxyaltronojirimycin
Yi-Ming Xu and Wei-Shan Zhou
pg 741; DOI:
10.1039/a605128f
PDF
First examples of arylazo derivatives of cyclooctatetraene
Zori V. Todres and Ghevork Ts. Hovsepyan
pg 747; DOI:
10.1039/a604933h
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Syntheses of gibberellins A93 and A94, natural products detected in wheat grain
Stuart Findlow Paul Gaskin Polly A. Harrison John R. Lenton Martin Penny and Christine L. Willis
pg 751; DOI:
10.1039/a604983d
PDF
Synthesis and biological evaluation of potential substrates for the isolation of the strigol receptor
Jan Willem J. F. Thuring Rolf Keltjens Gerard H. L. Nefkens and Binne Zwanenburg
pg 759; DOI:
10.1039/a604685a
PDF
Synthesis and biological evaluation of strigol analogues modified in the enol ether part
Jan Willem J. F. Thuring Angelique A. M. A. van Gaal Sander J. Hornes Margreet M. de Kok Gerard H. L. Nefkens and Binne Zwanenburg
pg 767; DOI:
10.1039/a604852h
PDF
Synthesis and stereochemistry of some new brominated spiro 1,3-dioxanes
Ion Grosu Brígida del Carmen Camacho Alfredo Toscano Gerard Plé Sorin Mager Roberto Martínez and Ruben Ramirez Gavino
pg 775; DOI:
10.1039/a604734c
PDF
Reactions of sulfonyl chlorides with silyl enol ethers catalysed by a ruthenium(II) phosphine complex: convenient synthesis of -keto sulfones
Nobumasa Kamigata Kumiko Udodaira and Toshio Shimizu
pg 783; DOI:
10.1039/a604466b
PDF
Formation and synthetic use of oxygen-centred radicals with (diacetoxyiodo)arenes
Hideo Togo Takahito Muraki Yoichiro Hoshina Kentaro Yamaguchi and Masataka Yokoyama
pg 787; DOI:
10.1039/a603446b
PDF

Issue 6


Dispiroketals in synthesis. Part 23.1 A new route to (+)-D-conduritol B from myo-inositol
Jean E. Innes Paul J. Edwards and Steven V. Ley
pg 795; DOI:
10.1039/a700422b
PDF
Copper(I)-catalysed homocoupling of organosilicon compounds: synthesis of biaryls, dienes and diynes
Suk-Ku Kang Tae-Hyun Kim and Sung-Jae Pyun
pg 797; DOI:
10.1039/a608384f
PDF
Lithium tri-tert-butylzincate as a chemoselective metallating reagent for functionalized organic halides
Yoshinori Kondo Michihiko Fujinami Masanobu Uchiyama and Takao Sakamoto
pg 799; DOI:
10.1039/a608294g
PDF
Synthesis of (5 -cyclopentadienyl)-1-(4-benzyloxycarbonyl-3,4-dihydroquinoxalin-2-yl )et hene-1,2-dithiolatocobalt(III) and (5-cyclopentadienyl)-1-[2-(N, N -dimethylaminomethyleneamino)-3-methyl-4-oxopteridin-6-yl]ethene-1,2 -di thiolatocobalt(III)
Andrew Dinsmore Jacqueline H. Birks C. David Garner and John A. Joule
pg 801; DOI:
10.1039/a607019a
PDF
Copper-catalysed coupling of undec-10-enylmagnesium bromide with -functionalised halogenoalkanes as a key reaction for the synthesis of novel bipolar phospholipids with different head groups and chain length
Ulrich F. Heiser and Bodo Dobner
pg 809; DOI:
10.1039/a606855c
PDF
Sulfur-controlled 5-exo selective aryl radical cyclisation of N-vinylic 2-bromobenzamides: synthesis of lennoxamine and chilenine
Hiroyuki Ishibashi Hirotaka Kawanami and Masazumi Ikeda
pg 817; DOI:
10.1039/a606723i
PDF
Preparation and reaction of 2-chloro-3,3-difluorocyclopropenylzinc reagent
Yeon-Tae Jeong Ji-Hun Jung and Sam-Kwon Choi
pg 823; DOI:
10.1039/a605422f
PDF
Biosynthesis of the fungal metabolite, piliformic acid (2-hexylidene-3-methylsuccinic acid)
Nicola C. J. E. Chesters and David O'Hagan
pg 827; DOI:
10.1039/a606589i
PDF
Acid-promoted isomerisation of 1-acceptor-1-sulfenyl-substituted 2-vinylcyclopropanes with C1–C2 bond fission and novel 1,5-sulfenyl rearrangement
Tetsuo Iwama Harutoshi Matsumoto and Tadashi Kataoka
pg 835; DOI:
10.1039/a606579a
PDF
Syntheses of thunbergols and - and -cembra-2,7,11-triene-4,6-diols
Peter C. Astles and Eric J. Thomas
pg 845; DOI:
10.1039/a606551a
PDF
Diastereospecific approach to ()-samin and 2,6-diaryl-3,7-dioxabicyclo[3.3.0]octane (furofuran) lignans using the Ireland–Claisen rearrangement of unsaturated oxamacrolides
Hilary M. Hull née Bradley and David W Knight
pg 857; DOI:
10.1039/a606545g
PDF
Carbonylative coupling of organozinc reagents in the presence and absence of aryl iodides: synthesis of unsymmetrical and symmetrical ketones
Richard F. W. Jackson Debra Turner and Michael H. Block
pg 865; DOI:
10.1039/a606394b
PDF
Versatile solid-phase thiolytic reduction of azido and N-Dts groups in the synthesis of haemoglobin (67–76) O-glycopeptides and photoaffinity labelled analogues to study glycan T-cell specificity
Ernst Meinjohanns Morten Meldal Teis Jensen Ole Werdelin Luisa Galli-Stampino Søren Mouritsen and Klaus Bock
pg 871; DOI:
10.1039/a606725e
PDF
Photochemical synthesis of pyrrole derivatives by desulfurization of 2,5-dihydro-1H-pyrrole-2-thiones and [2 + 2] cycloaddition of 2,5-dihydro-1H-pyrrole-2-thiones with alkenes
Takehiko Nishio
pg 885; DOI:
10.1039/a606211c
PDF
Diacetone-glucose architecture as a chirality template. Part 9.1 Enantioselective synthesis of (R)-mevalonolactone and (R)-[2H9]mevalonolactone on carbohydrate template
Masashi Kishida Noriaki Yamauchi Keiju Sawada Yuji Ohashi Tadashi Eguchi and Katsumi Kakinuma
pg 891; DOI:
10.1039/a606208c
PDF
Desilylative elimination of the quinazolinone ring from 1-(4-oxoquinazolin-3-yl)-2-silylaziridines; preparation of an N–H aziridine in high enantiomeric excess by in situ nucleophilic addition to the derived azirine
Robert S. Atkinson Michael P. Coogan and Ian S. T. Lochrie
pg 897; DOI:
10.1039/a606092g
PDF
1,3-Dipolar cycloaddition approach to the construction of new bis-heterocycles from thymine as potential non-nucleoside reverse transcriptase inhibitors
Caroline Perez Yves L. Janin David R. Adams Claude Monneret and David S. Grierson
pg 901; DOI:
10.1039/a605995c
PDF
New approach to AI-77B: stereoselective construction of a potential precursor of the amino acid side chain
Chisato Mukai Motonori Miyakawa and Miyoji Hanaoka
pg 913; DOI:
10.1039/a605901e
PDF
Pigments of fungi. Part 43.1,2 Cardinalins 1–6, novel pyranonaphthoquinones from the fungus Dermocybe cardinalis Horak
Malcolm S. Buchanan Melvyn Gill and Jin Yu
pg 919; DOI:
10.1039/a605900g
PDF
Exploitation of differential reactivity of the carbon–chlorine bonds in 1,3-dichloroisoquinoline. Routes to new N,N-chelate ligands and 1,3-disubstituted isoquinolines
Alan Ford Ekkehard Sinn and Simon Woodward
pg 927; DOI:
10.1039/a605827b
PDF
Synthesis and oxidation of chiral 2-thiazolines (4,5-dihydro-1,3-thiazoles)
R. Alan Aitken David P. Armstrong Ronald H. B. Galt and Shaun T. E. Mesher
pg 935; DOI:
10.1039/a605539g
PDF
Tris(2,4-pentanedionato)vanadium-catalysed cyclotrimerization and polymerization of 4-(N,N-dimethylamino)phenylethyne: X-ray structure of 1,2,4-tris[4-(N,N -dimethylamino)phenyl]benzene
J. Gonzalo Rodríguez Rosa Martín-Villamil and Isabel Fonseca
pg 945; DOI:
10.1039/a605474i
PDF
Synthesis of indole substituted dihydro- and tetrahydro-isoxazoles via 1,3-dipolar cycloadditions of C-(1-methylindol-2-yl)-N -methylnitrone with unsaturated carbonyl derivatives and a study of their acid-induced intramolecular cyclizations
Elizabeth Malamidou-Xenikaki Xenophon N. Stampelos Evdoxie Coutouli-Argyropoulou Christine J. Cardin Susana Teixeira and Constantin A. Kavounis
pg 949; DOI:
10.1039/a604788b
PDF
Juncins G and H: new briarane diterpenoids of the Indian Ocean gorgonian Junceella juncea Pallas
Ammanamanchi S. R. Anjaneyulu and Nidasanametla S. Kameswara Rao
pg 959; DOI:
10.1039/a604271f
PDF
Synthesis and crystal structure of enantiopure N-tritylaziridin-2-ylmethanols from L-serine and L-threonine
Johannes G. H. Willems Marco C. Hersmis René de Gelder Jan M. M. Smits Jeannet B. Hammink F. Jan Dommerholt Lambertus Thijs and Binne Zwanenburg
pg 963; DOI:
10.1039/a603801h
PDF
Parasite glycoconjugates. Part 6.1 Chemical synthesis of phosphorylated penta- and hepta-saccharide fragments of Leishmania major antigenic lipophosphoglycan
Andrei V. Nikolaev Gregory M. Watt Michael A. J. Ferguson and John S. Brimacombe
pg 969; DOI:
10.1039/a603800j
PDF
Synthesis of polyfluoroalkylated bicyclic and tricyclic heterocyclic compounds
Yan-Song Liu and Wei-Yuan Huang
pg 981; DOI:
10.1039/a603071h
PDF

Issue 7


Radical cyclisation with high diastereofacial selectivity: asymmetric synthesis of (
Masataka Ihara Akira Katsumata and Keiichiro Fukumoto
pg 991; DOI:
10.1039/a700834a
PDF
Reaction of 2-alkylamino-1-azaazulenes with N-phenylbenzylideneamine N-oxide; one pot synthesis of the 12H-11,12,13-triazaazuleno[2,1-b ]fluorene ring system
Noritaka Abe Haruhiko Matsuda Yoshikazu Sugihara and Akikazu Kakehi
pg 993; DOI:
10.1039/a700645d
PDF
Convenient synthesis of silyl substituted butadienes; a new route to silicon tethered intramolecular Diels–Alder reaction precursors
Klaus Kahle Patrick J. Murphy Jonathan Scott and Roberta Tamagni
pg 997; DOI:
10.1039/a700520b
PDF
Enzymatic glycosidation in dry media under microwave irradiation
Mirjana Gelo-Pujic Eryka Guibé-Jampel André Loupy and Antonio Trincone
pg 1001; DOI:
10.1039/a700144d
PDF
Vacuum–thermal fragmentation and ring cleavage of 1-(N-substituted-pyrrol-2-yl)-3-tosyltriazene tetraalkylammonium salts to 4-cyano-1-azabuta-1,3-dienes
Daniele Nanni and Paolo Zanirato
pg 1003; DOI:
10.1039/a606957f
PDF
-Arylation of ketones by aryllead triacetates. Effect of methyl and phenyl substitution at the position
Jacqueline Morgan John T. Pinhey and Bruce A. Rowe
pg 1005; DOI:
10.1039/a607543f
PDF
5-(Alk-1-enyl)-1,2,3,6-tetrahydropyridines as congeners of streptazolin
Martin Kratzel and Alexander Weigl
pg 1009; DOI:
10.1039/a607309c
PDF
D-Erythronolactone as a C4 building unit. Part 2.1 A short and efficient synthesis of both enantiomers of epi-muricatacin, a diastereoisomer of the native acetogenin from Annona muricata
Andreas Gypser Marcus Peterek and Hans-Dieter Scharf
pg 1013; DOI:
10.1039/a607158i
PDF
Synthesis of tetrahydroquinolines, hexahydrobenzoindolizines and an aryl phosphonate linker for the generation of catalytic antibodies
Concepción González-Bello Chris Abell and Finian J. Leeper
pg 1017; DOI:
10.1039/a606968a
PDF
Synthesis of high molecular mass condensed tannin by cationic polymerization of flavan 3,4-carbonate
Satoshi Yoneda Haruo Kawamoto and Fumiaki Nakatsubo
pg 1025; DOI:
10.1039/a606783b
PDF
Investigation of the configurational stability of lithiated phosphine oxides using the Hoffmann test: X-ray structures of (2S*,3S*,4R *)-2-(N,N -dibenzylamino)-4-diphenylphosphinoyl-1-phenylpentan-3-ol and (2S*,4S*)-2-(N, N -dibenzylamino)-4-diphenylphosphinoyl-1-phenylpentan-3-one
Peter O'Brien Harold R. Powell Paul R. Raithby and Stuart Warren
pg 1031; DOI:
10.1039/a606720d
PDF
Selective mono-N-methylation of primary aromatic amines by dimethyl carbonate over faujasite X- and Y-type zeolites
Maurizio Selva Andrea Bomben and Pietro Tundo
pg 1041; DOI:
10.1039/a606684d
PDF
New phenanthrene systems: spiro-fused tricyclic phenanthro-1,2,4-triazolo-[4,3-d]-1,2,4-triazines and -[3,4-d]-1,2,5-oxadiazines: ring expansions of N-methylphenanthroazoliums
Richard N. Butler John M. McMahon Peter D. McDonald Carmel S. Pyne Simon Schambony Patrick McArdle and Desmond Cunningham
pg 1047; DOI:
10.1039/a605770e
PDF
Synthesis of functionalised fluorescent dyes and their coupling to amines and amino acids
Mark S. J. Briggs Ian Bruce James N. Miller Christopher J. Moody Adrian C. Simmonds and Elizabeth Swann
pg 1051; DOI:
10.1039/a605012c
PDF
Synthesis, structure and stability of E/Z-isomers of novel conjugated enamines prepared from 9-arylmethyl- or 9-arylpropenyl-9H-carbazole with arylmethyleneanilines
Martino Paventi and Allan S. Hay
pg 1059; DOI:
10.1039/a604969i
PDF
Derivatives of L-pyrimidylalanine
Gury Zvilichovsky and Vadim Gurvich
pg 1069; DOI:
10.1039/a604879j
PDF
Conformationally locked carbocyclic nucleosides built on a bicyclo[3.1.0]hexane template with a fixed Southern conformation. Synthesis and antiviral activity
Abdallah Ezzitouni and Victor E. Marquez
pg 1073; DOI:
10.1039/a604352f
PDF

Issue 8


Expeditious synthesis of monosulfated thio-linked disaccharides
José A. Calvo-Asín Francisco G. Calvo-Flores Juan M. Exposito-López Fernando Hernández-Mateo Juan J. García-López Joaquín Isac-García Francisco Santoyo-González and Antonio Vargas-Berenguel
pg 1079; DOI:
10.1039/a701345k
PDF
Novel synthesis of the indolizidine alkaloid skeleton with appropriate functionality and stereochemistry for use as a chiral scaffold
Elizabeth Farrant and John Mann
pg 1083; DOI:
10.1039/a701193h
PDF
Regioselective methanesulfonylation of toluene catalysed by cation-exchanged zeolite
Keith Smith Gordon M. Ewart and Kenneth R. Randles
pg 1085; DOI:
10.1039/a701025g
PDF
Synthesis of tricholomenyn A and epitricholomenyn A by a palladium-catalysed -halo enone coupling route
Andrew E. Graham and Richard J. K. Taylor
pg 1087; DOI:
10.1039/a700980a
PDF
Studies towards the taxane ring system via a cascade macrocyclisation–transannulation strategy
Stephen J. Houldsworth Gerald Pattenden David C. Pryde and Nicholas M. Thomson
pg 1091; DOI:
10.1039/a700784a
PDF
Synthesis of conjugated dienes from vinyl epoxides, vinyl acetonides and 2,5-dihydrofurans via zirconocene-mediated deoxygenation
Sunggak Kim and Kwan Hee Kim
pg 1095; DOI:
10.1039/a608593h
PDF
An in-depth study of the biotransformation of nitriles into amides and/or acids using Rhodococcus rhodochrous AJ2701
Otto Meth-Cohn and Mei-Xiang Wang
pg 1099; DOI:
10.1039/a607977f
PDF
Synthetic studies relevant to biosynthetic research on vitamin B12. Part 12.1 Modification of the periphery of chlorins and isobacteriochlorins
James J. De Voss Finian J. Leeper and Alan R. Battersby
pg 1105; DOI:
10.1039/a607852d
PDF
Chelation-assisted nucleophilic aromatic substitution of 2-sulfonyl-substituted 1-methoxynaphthalenes by Grignard reagents: factors determining the activating ability of the 2-sulfonyl substituents1,2
Tetsutaro Hattori Mikio Suzuki Noriyuki Tomita Ayanobu Takeda and Sotaro Miyano
pg 1117; DOI:
10.1039/a607663g
PDF
Synthesis of -dimorphecolic acid exploiting highly stereoselective reduction of a side-chain carbonyl group in a -allyltricarbonyliron lactone complex
Steven V. Ley and Graham Meek
pg 1125; DOI:
10.1039/a607376j
PDF
A new route to -fluoroalkylphosphonates
Rachel Waschbüsch John Carran and Philippe Savignac
pg 1135; DOI:
10.1039/a607288g
PDF
Improved synthesis for the rodenticides, diphenacoum and brodifacoum
Pieter S. van Heerden Barend C. B. Bezuidenhoudt and Daneel Ferreira
pg 1141; DOI:
10.1039/a607269k
PDF
5-Nitrofuran-2-ylmethyl group as a potential bioreductively activated pro-drug system
Jane M. Berry Corrine Y. Watson William J. D. Whish and Michael D. Threadgill
pg 1147; DOI:
10.1039/a607202j
PDF
Thermal fragmentation reactions of 1,4,2-dithiazines and 1,4,2,5-dithiadiazines in the presence of dienophiles: synthesis of 1,4-dithiine derivatives. X-Ray crystal structures of a 1,4,2-dithiazine 1,1-dioxide and a 1,4,2,5-dithiadiazine derivative
Martin R. Bryce Shimon Yoshida Andrei S. Batsanov and Judith A. K. Howard
pg 1157; DOI:
10.1039/a606970c
PDF
Synthesis and palladium-catalysed transformation of an annelated barrelene
Gerald Dyker Thomas Kerl Peter G. Jones Ina Dix and Peter Bubenitschek
pg 1163; DOI:
10.1039/a606857j
PDF
Radical-mediated transannulation reactions in humulene. A new synthesis of substituted bicyclo[6.3.0]undeca-4,9-dienes
Alexander J. Blake Amanda R. Gladwin Gerald Pattenden and Allison J. Smithies
pg 1167; DOI:
10.1039/a606811a
PDF
The synthesis of a tricyclic pyrrolopyrimidine related to N 6-hydroxyadenine
David M. Williams Dmitry Yu. Yakovlev and Daniel M. Brown
pg 1171; DOI:
10.1039/a606472h
PDF
Synthesis of 14,17-propano analogues of estradiol
James R. Bull Clarissa Hoadley Pia G. Mountford and Lynne M. Steer
pg 1179; DOI:
10.1039/a606242c
PDF
Selective preparation of polycyclic aromatic hydrocarbons. Part 4.1 New synthetic route to anthracenes from diphenylmethanes using Friedel–Crafts intramolecular cyclization
Takehiko Yamato Naozumi Sakaue Naoki Shinoda and Koji Matsuo
pg 1193; DOI:
10.1039/a606205i
PDF
Selective preparation of polycyclic aromatic hydrocarbons. Part 5.1 Bromination of 2,7-di-tert-butylpyrene and conversion into pyrenoquinones and their pyrenoquinhydrones
Takehiko Yamato Masakazu Fujimoto Akira Miyazawa and Koji Matsuo
pg 1201; DOI:
10.1039/a606200h
PDF
New asymmetric route to bridged indole alkaloids: formal enantiospecific syntheses of (-)-suaveoline, (-)-raumacline and (-)-Nb-methylraumacline
Patrick D. Bailey Ian D. Collier Sean P. Hollinshead Madeleine H. Moore Keith M. Morgan David I. Smith and John M. Vernon
pg 1209; DOI:
10.1039/a606081a
PDF
Syntheses of symmetrically substituted 5-alkyl- and 5-aryl-dihydrodipyrrins and of porphyrins and bisporphyrins therefrom
David A. Lee and Kevin M. Smith
pg 1215; DOI:
10.1039/a606054d
PDF
Novel synthesis of 10-membered cyclic bis-ethers from 4-(N-alkylanilino)but-2-yn-1-ols 1
Krishna C. Majumdar Gour H. Jana and Udayan Das
pg 1229; DOI:
10.1039/a606047a
PDF
Control of the rotational barrier and spatial disposition of the N-(2-methylphenyl) group in succinimides by substituent and solvent effects
Keiki Kishikawa Kazumi Yoshizaki Shigeo Kohmoto Makoto Yamamoto Kentaro Yamaguchi and Kazutoshi Yamada
pg 1233; DOI:
10.1039/a605896e
PDF
Productivity in synthesis: a mixture protocol to raise compound output is demonstrated for asymmetric cyclopropanation of allyl alcohols
Michael D. Turnbull
pg 1241; DOI:
10.1039/a605895g
PDF
Novel class of difluorovinylphosphonate analogues of PEP
Aparecida M. Kawamoto and Malcolm M. Campbell
pg 1249; DOI:
10.1039/a603094g
PDF

Issue 9


Stereoselective enzymatic galactosylation of C-glucosides
Luigi Panza Pietro L. Chiappini Giovanni Russo Daniela Monti and Sergio Riva
pg 1255; DOI:
10.1039/a701747b
PDF
Anti-Markovnikov opening of trisubstituted epoxy alcohols: application in the synthesis of 2-methyl-1,3-diols
Tushar K. Chakraborty and Shantanu Dutta
pg 1257; DOI:
10.1039/a701536d
PDF
Constructing the side-chain of the polyketide herbicide herboxidiene: a protocol for the synthesis of enantiomerically enriched C-11 to C-19 fragments
Martin G. Banwell Chinh T. Bui David C. R. Hockless and Gregory W. Simpson
pg 1261; DOI:
10.1039/a701360d
PDF
Novel unsymmetrical monofunctionalized lutetium and dysprosium bisphthalocyanines with seven crown-ether units and one hexyl hexanoate side-group
Didier Pernin Klaus Haberroth and Jacques Simon
pg 1265; DOI:
10.1039/a701305a
PDF
Cyclisations of benzenesulfenyl chloride adducts with conjugated silyloxyenones: a new stereoselective reaction in the synthesis of 4,5-dihydrofuran-3(2H)-ones
Conor C. Colins Michael F. Cronin Humphrey A. Moynihan and Daniel G. McCarthy
pg 1267; DOI:
10.1039/a700835j
PDF
Photochemical behaviour of -diketones on a silica gel surface: a novel photoreaction by intramolecular trapping of an excited ketone carbonyl oxygen by an aryl group
Tadashi Hasegawa Manabu Imada Yoshihiro Imase Yuko Yamazaki and Michikazu Yoshioka
pg 1271; DOI:
10.1039/a700141j
PDF
Laser-induced enantioenrichment of tartaric acid via a multiphoton absorption process
Yuichi Shimizu
pg 1275; DOI:
10.1039/a608453b
PDF
Synthesis of the enantiomers of myo-inositol 1,2,4,5-tetrakisphosphate, a regioisomer of myo-inositol 1,3,4,5-tetrakisphosphate
Stephen J. Mills and Barry V. L. Potter
pg 1279; DOI:
10.1039/a608337d
PDF
Metal-catalysed reactions of imines with ethyl diazoacetate leading to aziridines
Kaare G. Rasmussen and Karl Anker Jørgensen
pg 1287; DOI:
10.1039/a608098g
PDF
Asymmetric addition of trimethylsilyl cyanide to aldehydes catalysed by chiral (salen)TiIV complexes
Yuri Belokon' Massimilano Flego Nicolai Ikonnikov Margarita Moscalenko Michael North Charles Orizu Vitali Tararov and Michela Tasinazzo
pg 1293; DOI:
10.1039/a608097i
PDF
Synthesis of agonists and antagonists for central glutamate receptors by a novel ring switching strategy1
Andrew N. Bowler Andrew Dinsmore Paul M. Doyle and Douglas W. Young
pg 1297; DOI:
10.1039/a608067g
PDF
Bicyclo[3.3.1]nonanes as synthetic intermediates. Part 19.1 Asymmetric cleavage of -azabicyclo[3.n.1]alkan-3-ones at the fork head
Takefumi Momose Minoru Toshima Naoki Toyooka Yoshiro Hirai and Conrad Hans Eugster
pg 1307; DOI:
10.1039/a607812e
PDF
Bicyclo[3.3.1]nonanes as synthetic intermediates. Part 20.1 Asymmetric synthesis of the indolizidine alkaloids monomorine I and indolizidine 223AB
Takefumi Momose Minoru Toshima Sumie Seki Yayoi Koike Naoki Toyooka and Yoshiro Hirai
pg 1315; DOI:
10.1039/a607981d
PDF
Simple preparation of fused pyrrolo[2,3-b]pyrrolidinones and pyrrolo[2,3-c]pyridazinones1
Yoshinari Okamoto Yumiko Kaneda Tetsuo Yamasaki Tadashi Okawara and Mitsuru Furukawa
pg 1323; DOI:
10.1039/a607816h
PDF
In search of open-chain 1,3-stereocontrol
Asun Barbero David C. Blakemore Ian Fleming and Robert N. Wesley
pg 1329; DOI:
10.1039/a607545b
PDF
A new chiral synthesis of bullfrog bile sterol 5-ranol
Don W. Harney and Theodore A. Macrides
pg 1353; DOI:
10.1039/a607850h
PDF
Alkaline earth metal-sensing anthracene fluorophore-hosts
Satoru Iwata Hideo Matsuoka and Kiyoshi Tanaka
pg 1357; DOI:
10.1039/a607688b
PDF
Acylation of in situ generated trimethylsilyl diethylphosphonoacetate using magnesium chloride–triethylamine: a practical synthesis of -keto phosphonates
Dae Young Kim Myeon Sik Kong and Kilsung Lee
pg 1361; DOI:
10.1039/a607683a
PDF
Internally quenched fluorogenic, -helical dimeric peptides and glycopeptides for the evaluation of the effect of glycosylation on the conformation of peptides
Seema Mehta Morten Meldal Vito Ferro Jens Ø. Duus and Klaus Bock
pg 1365; DOI:
10.1039/a607624f
PDF
o-Nitroaniline derivatives. Part 14.1,2 Cyclisations leading to benzimidazole N-oxides, N-hydroxybenzimidazolones and N-hydroxyquinoxaline-2,3-diones: a mechanistic borderline
Pamela A. Collins Cafiero Colin S. French Michael D. McFarlane Raymond K. Mackie and David M. Smith
pg 1375; DOI:
10.1039/a607378f
PDF
Synthesis based on cyclohexadienes. Part 22.1 Formal syntheses of patchouli alcohol and norpatchoulenol
Krishna P. Kaliappan and G. S. R. Subba Rao
pg 1385; DOI:
10.1039/a607286k
PDF
Highly selective conversion of hydroxylated biaryls to dibenzofuran derivatives over zeolite catalyst
Attilio Arienti Franca Bigi Raimondo Maggi Pietro Moggi Massimo Rastelli Giovanni Sartori and Alessandra Trerè
pg 1391; DOI:
10.1039/a607282h
PDF
2,2,4,4,6-Penta-tert-butylbenzil: an unexpected product in the attempted coupling of tri-tert-butylbenzoyl chloride with magnesium–magnesium iodide
Joseph Frey and Zvi Rappoport
pg 1395; DOI:
10.1039/a607222d
PDF
Synthesis of the monomeric unit of -actinorhodin
Margaret A. Brimble Letecia J. Duncalf and Sara J. Phythian
pg 1399; DOI:
10.1039/a606765d
PDF
Retinoids and related compounds. Part 19.1 Syntheses of 9E- and 9Z-locked retinoic acid analogues and their transcriptional activities as ligands for retinoic acid receptors and retinoid X receptors
Yuko Katsuta Yukiko Aoyama Hisa Osone Akimori Wada and Masayoshi Ito
pg 1405; DOI:
10.1039/a606719k
PDF
Palladium-catalysed asymmetric allylic substitution: synthesis of - and -amino acids
Justin F. Bower Roshan Jumnah Andrew C. Williams and Jonathan M. J. Williams
pg 1411; DOI:
10.1039/a606586d
PDF
Synthesis of the aromatic unit of calicheamicin 1I
Yong-Zhou Hu and Derrick L. J. Clive
pg 1421; DOI:
10.1039/a605837j
PDF
Unexpected stereoselectivity in the Weiss–Cook condensation of dimethyl 1,3-acetonedicarboxylate with pentane-2,3-dione
Richard Vaughan Williams Vijay R. Gadgil Ashwani Vij James M. Cook Greg Kubiak and Qi Huang
pg 1425; DOI:
10.1039/a605817e
PDF
Glycosylation of Fmoc amino acids: preparation of mono- and di-glycosylated derivatives and their incorporation into Arg-Gly-Asp (RGD)-containing glycopeptides
Hiran Vegad Charles J. Gray Peter J. Somers and Anand S. Dutta
pg 1429; DOI:
10.1039/a604372k
PDF

Issue 10


Synthesis and reactions of 3,3-dibromodihydrodipyrrins
Chitoshi Kitamura and Yoshiro Yamashita
pg 1443; DOI:
10.1039/a700154a
PDF
A new synthetic method for the preparation of amino sugars through an allyl cyanate-to-isocyanate rearrangement
Yoshiyasu Ichikawa Masafumi Osada Ikuko I. Ohtani and Minoru Isobe
pg 1449; DOI:
10.1039/a700142h
PDF
Reactions involving fluoride ion. Part 42.1 Heterocyclic compounds from perfluoro-3,4-dimethylhexa-2,4-diene
Richard D. Chambers William K. Gray Steven J. Mullins and Stewart R. Korn
pg 1457; DOI:
10.1039/a608584i
PDF
The in situ generation of alk-1-ynyllead triacetates from terminal acetylenes by zinc–lead exchange and crystal structure of 2,4,7,9,13-pentamethyl-9-phenylethynyl-7,10-ethenospiro[5.5]undeca-1,4- diene-3,8-dione
Christopher J. Parkinson Trevor W. Hambley and John T. Pinhey
pg 1465; DOI:
10.1039/a608582b
PDF
The synthesis of alkylated or acylated nitroarene cyclopentadienyliron complexes: an alternative approach to the synthesis of arylated alkanoates
Alaa S. Abd-El-Aziz Waleed Boraie Najeeb Al-Salem Salwa A. Sadek and Karen M. Epp
pg 1469; DOI:
10.1039/a608578d
PDF
Preparation of -amino alcohols by carbon–carbon bond formation using substituted lithiomethylpyrrolidines
Iain Coldham Stuart Holman and Maria M. S. Lang-Anderson
pg 1481; DOI:
10.1039/a608576h
PDF
Reactions of 2-methyl-4H-pyrido[2,3-d][3,1]oxazin-4-one with active methylene compounds: a new efficient route to 3-substituted 4-hydroxy-1,8-naphthyridin-2(1H)-ones
Vassiliki Delieza Anastasia Detsi Vassilios Bardakos and Olga Igglessi-Markopoulou
pg 1487; DOI:
10.1039/a608509a
PDF
Mechanism of the Stevens rearrangement of ammonium ylides
Yasuhiro Maeda and Yoshiro Sato
pg 1491; DOI:
10.1039/a608492c
PDF
Synthesis of pendant polyaminopolycarboxylic acid crown ethers: potential ligands for MRI contrasting agents
B. Lakshmi A. Prabhavathi Devi and Madhavarao Nagarajan
pg 1495; DOI:
10.1039/a608452d
PDF
Building units for N-backbone cyclic peptides. Part 4.1 Synthesis of protected N-functionalized alkyl amino acids by reductive alkylation of natural amino acids
Gal Bitan Dan Muller Ron Kasher Evgenia V. Gluhov and Chaim Gilon
pg 1501; DOI:
10.1039/a608389g
PDF
Aryltricyclospirodienones; novel steroid mimics as inhibitors of aromatase
David Hobbs-Mallyon Warren Li and Donald A. Whiting
pg 1511; DOI:
10.1039/a608338b
PDF
Diastereoselective acyclic aza-[2,3] Wittig sigmatropic rearrangements
James C. Anderson Stephen C. Smith and Martin E. Swarbrick
pg 1517; DOI:
10.1039/a608226b
PDF
Secondary mould metabolites: Part 53.1 Transformation of the protoilludane sesquiterpene tsugicoline A into a sterpurane derivative and its microbiological reduction
Alberto Arnone Cristiana De Gregorio Gianluca Nasini and Orso Vajna De Pava
pg 1523; DOI:
10.1039/a608174f
PDF
Enantioselective synthesis of -hydroxyphosphonates through asymmetric Pudovik reactions with chiral lanthanoid and titanium alkoxides
Tsutomu Yokomatsu Takehiro Yamagishi and Shiroshi Shibuya
pg 1527; DOI:
10.1039/a608161d
PDF
Novel photochemical behaviour of the oximes and hydrazones of ,-unsaturated carbonyl compounds
Diego Armesto Ana Ramos Maria J. Ortiz William M. Horspool Maria J. Mancheño Olga Caballero and Elena P. Mayoral
pg 1535; DOI:
10.1039/a607435i
PDF
A radio-iodinated abscisic acid photoaffinity probe
Andrew D. Kohler Michael H. Beale Ruth Rollason D. H. Paul Barratt Mervyn J. Lewis R. M. Van der Meulen and Mei Wang
pg 1543; DOI:
10.1039/a607307g
PDF
Synthesis of functionalised indolines by radical-polar crossover reactions
John A. Murphy Faiza Rasheed Stéphane Gastaldi T. Ravishanker and Norman Lewis
pg 1549; DOI:
10.1039/a607060d
PDF
Nitration of ,-unsaturated esters. Evidence for positive charge build-up adjacent to carbonyl carbon
Stuart A. Hewlins John A. Murphy Jian Lin David E. Hibbs and Michael B. Hursthouse
pg 1559; DOI:
10.1039/a607170h
PDF
Novel synthesis of degradation products of carotenoids, megastigmatrienone analogues and blumenol-A
Nobuhiko Ito Takeaki Etoh Hisahiro Hagiwara and Michiharu Kato
pg 1571; DOI:
10.1039/a607028k
PDF
Asymmetric 1,3-dipolar cycloaddition of optically active trifluoromethylated ,-unsaturated aryl sulfones with nitrones: the use of o-dialkylaminoethyl chiral auxiliaries
Hiroyasu Tsuge Takashi Okano Shoji Eguchi and Hiroshi Kimoto
pg 1581; DOI:
10.1039/a606890a
PDF
Harzianin HB I, an 11-residue peptaibol from Trichoderma harzianum: isolation, sequence, solution synthesis and membrane activity
Isabelle Augeven-Bour Sylvie Rebuffat Catherine Auvin Christophe Goulard Yann Prigent and Bernard Bodo
pg 1587; DOI:
10.1039/a605629f
PDF

Issue 11


Efficient cyclopropanation of C60 starting from malonates
Xavier Camps and Andreas Hirsch
pg 1595; DOI:
10.1039/a702055d
PDF
Synthesis of (difluoromethyl)phosphonate azasugars designed as inhibitors for glycosyl transferases
Jean-Bernard Behr Claude Mvondo Evina Nga Phung and Georges Guillerm
pg 1597; DOI:
10.1039/a700800g
PDF
Short path syntheses of -diozonides by sequential ozonolyses of acetylenes and O-methyl oximes
Yuxiang Dong Karl Griesbaum and Kevin J. McCullough
pg 1601; DOI:
10.1039/a700989e
PDF
Gas-phase pyrolysis of 1-(2-azidophenyl)imidazole
Alexander J. Blake Bernard A. J. Clark Hamish McNab and Craig C. Sommerville
pg 1605; DOI:
10.1039/a700457e
PDF
Unexpected formation of highly stabilized tetrakis-(2-alkoxyphenyl)bismuthonium salts in the oxidation of tris-(2-alkoxyphenyl)bismuthanes with iodosylbenzene
Hitomi Suzuki Tohru Ikegami and Nagao Azuma
pg 1609; DOI:
10.1039/a700379j
PDF
Reaction of furans with trithiazyl trichloride: a new synthesis of isothiazoles
Xiao-Lan Duan Ross Perrins and Charles W. Rees
pg 1617; DOI:
10.1039/a700358g
PDF
Conversion of carbonimidodithioates to carbamates
Mariappan Anbazhagan T. Indrasena Reddy and Srinivasachari Rajappa
pg 1623; DOI:
10.1039/a700166e
PDF
Synthesis of homoallylic (but-3-enylic) alcohols from aldehydes with allylic chlorides, tin(II) chloride and potassium iodide in water
Didier Houllemare Francis Outurquin and Claude Paulmier
pg 1629; DOI:
10.1039/a608487g
PDF
Synthesis of methyl secolonitoside
Richard T. Brown Stephen P. Mayalarp and Joanne Watts
pg 1633; DOI:
10.1039/a608247e
PDF
-Halogeno polyenals: preparation and application to a one-pot synthesis of polyenals from carbonyl compounds
David Soullez Gérard Plé and Lucette Duhamel
pg 1639; DOI:
10.1039/a608187h
PDF
Chemistry of the mycalamides: antiviral and antitumour compounds from a New Zealand marine sponge. Part 6.1–3 The synthesis and testing of analogues of the C(7)–C(10) fragment
Andrew D. Abell John W. Blunt Glenn J. Foulds and Murray H. G. Munro
pg 1647; DOI:
10.1039/a608168a
PDF
Chemistry and X-ray crystallographic structure of N-protected (5-oxo-1,3-oxazolidin-4-yl)acetic acids: versatile intermediates in the synthesis of peptidomimetics
Andrew D. Abell Ross A. Edwards and Mark D. Oldham
pg 1655; DOI:
10.1039/a608165g
PDF
Preparation and biological activity of tricyclic non-steroidal inhibitors of human steroid 5-reductase
Andrew D. Abell Martin Brandt Mark A. Levy and Dennis A. Holt
pg 1663; DOI:
10.1039/a608169j
PDF
Furan-2(3H)- and -2(5H)-ones. Part 7.1 Photochemical behaviour of tetrahydro- and hexahydro-isobenzofuran-1-one systems: a mechanistic and exploratory study
Osamu Muraoka Genzoh Tanabe and Yuko Igaki
pg 1669; DOI:
10.1039/a608122c
PDF
Alkylation of chiral 2-(aminomethyl)oxazolines
Marc Le Bail David J. Aitken Fabrice Vergne and Henri-Philippe Husson
pg 1681; DOI:
10.1039/a608030h
PDF
Synthesis and Diels–Alder reactions of 2-acetamido-3-phenylthiobuta-1,3-diene and its derivatives
Shang-Shing P. Chou Tahsin J. Chow Chien-Hung Hsu Chengda Yang Shu-Hua Long and Chih-Da Lin
pg 1691; DOI:
10.1039/a607817f
PDF
Indolisation of 1-decalone and the reactions of the products with oxygen and with nucleophiles
David W. Brown Mary F. Mahon Aleyamma Ninan and Malcolm Sainsbury
pg 1699; DOI:
10.1039/a607577k
PDF
Total synthesis of ()-furoscrobiculin B
Maki Seki Toshihiro Sakamoto Hiroshi Suemune and Ken Kanematsu
pg 1707; DOI:
10.1039/a607164c
PDF
Bacterial dioxygenase-catalysed dihydroxylation and chemical resolution routes to enantiopure cis-dihydrodiols of chrysene
Derek R. Boyd Narain D. Sharma Rajiv Agarwal Sol M. Resnick Mark J. Schocken David T. Gibson Jane M. Sayer Haruhiko Yagi and Donald M. Jerina
pg 1715; DOI:
10.1039/a606686k
PDF
Synthesis and conformational studies of tetrahydroxy[3.1.3.1]metacyclophanes and electrophilic aromatic substitution of their tetramethoxy derivatives
Takehiko Yamato Yoshiyuki Saruwatari and Masashi Yasumatsu
pg 1725; DOI:
10.1039/a606358f
PDF
Synthesis and conformational studies of regio- and conformational isomers derived by O-alkylation of tetrahydroxy[3.1.3.1]metacyclophane1
Takehiko Yamato Yoshiyuki Saruwatari and Masashi Yasumatsu
pg 1731; DOI:
10.1039/a606354c
PDF
Asymmetric hydrolysis of pro-chiral 3,3-disubstituted 2,4-diacetoxycyclohexa-1,4-dienes
Philippe Renouf Jean-Marie Poirier and Pierre Duhamel
pg 1739; DOI:
10.1039/a606001c
PDF
Preparation of optically active photopyridone by lipase-catalysed asymmetric resolution1
Hiroshi Hongo Kazuto Iwasa Chizuko Kabuto Hisao Matsuzaki and Hiroto Nakano
pg 1747; DOI:
10.1039/a605698i
PDF
Synthesis of ()-trans-cyclohexa-3,5-diene-1,2-diol derivatives from myo-inositol
Hari Babu Mereyala and Madhavi Pannala
pg 1755; DOI:
10.1039/a605576a
PDF

Issue 12


Design of new chiral tetraol host compounds, trans-1,4-bis[3-(o-chlorophenyl)-3-hydroxy-3- phenylprop-1-ynyl]-1,4-dihydroxycyclohexa-2,5-diene and its tetrahalogeno derivatives
Fumio Toda and Tomonori Shinyama
pg 1759; DOI:
10.1039/a701874f
PDF
Enantioselective Pummerer-type rearrangement by reaction of O-silylated ketene acetal with enantiopure -substituted sulfoxides
Yasuyuki Kita Norio Shibata Seiji Fukui Masahiko Bando and Shigekazu Fujita
pg 1763; DOI:
10.1039/a702020a
PDF
Cleavage of (octaethyl-2,3-dihydroxychlorinato)nickel(II) to give the novel 2,3-dioxo-2,3-secochlorin system
Keith R. Adams Raymond Bonnett Philip J. Burke Antonio Salgado and María Asunción Vallés
pg 1769; DOI:
10.1039/a701152k
PDF
Retinoids and related compounds. Part 20.1 Synthesis of (11Z)-8,18-ethanoretinal and a conformational study of the rhodopsin chromophore
Akimori Wada Miho Sakai Yasushi Imamoto Yoshinori Shichida Masashige Yamauchi and Masayoshi Ito
pg 1773; DOI:
10.1039/a700796e
PDF
Regio- and stereo-chemical outcomes in the nucleophilic ring cleavage reactions of mono-epoxides derived from cis-1,2-dihydrocatechols
Martin G. Banwell Najiba Haddad Tomas Hudlicky Thomas C. Nugent Maureen F. Mackay and Sharon L. Richards
pg 1779; DOI:
10.1039/a700733g
PDF
Enantioselective synthesis of 2-isocephem and 2-isooxacephem antibiotics
Hajime Nitta Ikuo Ueda and Minoru Hatanaka
pg 1793; DOI:
10.1039/a700650k
PDF
Preparation and pyrolysis of 1-(pyrazol-5-yl)-1,2,3-triazoles and related compounds1
David Clarke Richard W. Mares and Hamish McNab
pg 1799; DOI:
10.1039/a700421d
PDF
Enantiospecific synthesis of (-)-5-epi-shikimic acid and (-)-shikimic acid
Shende Jiang Kevin J. McCullough Boualem Mekki Gurdial Singh and Richard H. Wightman
pg 1805; DOI:
10.1039/a700389g
PDF
Chemistry of zamoranic acid. Part 10. Homochiral hemisynthesis of pereniporin A
Julio G. Urones David Díez Patricio M. Gómez Isidro S. Marcos Pilar Basabe and Rosalina F. Moro
pg 1815; DOI:
10.1039/a700377c
PDF
Synthesis and conjugate additions of 2,3,4,9-tetrahydro-1H-xanthene-1,9-diones
Christopher D. Gabbutt John D. Hepworth Michael W. J. Urquhart and Luis Millan Vazquez de Miguel
pg 1819; DOI:
10.1039/a700375g
PDF
Synthesis of oligodeoxynucleotides containing 6-N-([13C]methyl)adenine and 2-N-([13C]methyl)guanine
Mechtild Hofmann Montse Acedo Patricia Fagan David Wemmer Ramon Eritja and Antonio R. Díaz
pg 1825; DOI:
10.1039/a700366h
PDF
Cleavage and reactions of some NH-BOC protected 1-aminopyrroles: a new one-pot route to pyrrolo[1,2-b][1,2,4]triazines together with spectroscopic and X-ray studies
Orazio A. Attanasi Lucia De Crescentini Elisabetta Foresti Giuseppe Gatti Raffaello Giorgi Francesca R. Perrulli and Stefania Santeusanio
pg 1829; DOI:
10.1039/a700355b
PDF
Stereoselective synthesis of (-)-metasequoic acid B
Antonio Abad Consuelo Agulló Manuel Arnó Angel Cantín Ana C. Cuñat Benjamín Meseguer and Ramón J. Zaragozá
pg 1837; DOI:
10.1039/a700354d
PDF
Phospholipase-A2-mediated stereoselective synthesis of (R)-1-O-alkylglycero-3-phosphate and alkyl-acyl analogues: application for synthesis of radiolabelled biosynthetic precursors of cell surface glycoconjugates of Leishmania donovani
Parmeshwari Sahai and Ram A. Vishwakarma
pg 1845; DOI:
10.1039/a700353f
PDF
Photochemical reactions of thiobenzamides bearing an allylic substituent on the nitrogen atom: double-bond migration via tandem 1,4- and 1,6-hydrogen transfer
Hiromu Aoyama
pg 1851; DOI:
10.1039/a700247e
PDF
Efficient synthesis of O-(2-acetamido-2-deoxy--D- glucopyranosyl)-serine and -threonine building blocks for glycopeptide formation
Uttam K. Saha and Richard R. Schmidt
pg 1855; DOI:
10.1039/a700210f
PDF
[4 + 2]Cycloaddition of indole derivatives with bismaleimides: a route to new biscarbazoles
Ulf Pindur Eugenia Gonzalez and Farokh Mehrabani
pg 1861; DOI:
10.1039/a608580f
PDF
Asymmetric hydrogenation of acrylic acid derivatives by novel chiral rhodium–phosphinediamine complex catalysts by selective ligation between two amino units of the ligand and electrostatic interaction
Issaku Yamada Munetaka Ohkouchi Motowo Yamaguchi and Takamichi Yamagishi
pg 1869; DOI:
10.1039/a608228i
PDF
Regioselective total synthesis of edulane and its angular analogue
Kandasamy Subburaj Modachur G. Murugesh and Girish K. Trivedi
pg 1875; DOI:
10.1039/a608227k
PDF
Toluene dioxygenase-catalysed oxidation route to angular cis-monohydrodiols and other bioproducts from bacterial metabolism of 1,2-dihydrobenzocyclobutene and derivatives
Derek R. Boyd Narain D. Sharma Timothy A. Evans Melanie Groocock John F. Malone Paul J. Stevenson and Howard Dalton
pg 1879; DOI:
10.1039/a608071e
PDF
Synthesis of 2-substituted 2-deoxyguanosines and 6-O-allylguanines via the activation of C-2 by a trifluoromethanesulfonate group
Christine Edwards Gernot Boche Thomas Steinbrecher and Susanne Scheer
pg 1887; DOI:
10.1039/a604559f
PDF
19-Hydroxy-5,19-cyclosteroids: synthesis, isomerization and ring opening
John F. Templeton Yangzhi Ling Weiyang Lin Helena Majgier-Baranowska and Kirk Marat
pg 1895; DOI:
10.1039/a604405k
PDF

Issue 13


Polymer supported perruthenate (PSP): a new oxidant for clean organic synthesis
Berthold Hinzen and Steven V. Ley
pg 1907; DOI:
10.1039/a703461j
PDF
TiCl4-promoted cross-coupling reaction of dialkyl 3,3,3-trifluoropropyl acetals for the preparation of CF3-containing functionalized compounds
Feng Hong and Chang-Ming Hu
pg 1909; DOI:
10.1039/a702402i
PDF
Convergent, enantioselective synthesis of the novel furanoditerpene (+)-taonianone through facially selective chiral olefin–ketene [2+2] cycloaddition
Alice Kanazawa Philippe Delair Mehrnaz Pourashraf and Andrew E. Greene
pg 1911; DOI:
10.1039/a701629h
PDF
Angular trifluoromethyl group. Part 6.1 Studies in the series of 19,19,19-trifluoroandrostenedione derivatives
Jean-Claude Blazejewski Jean Guilhem and Frédéric Le Guyader
pg 1913; DOI:
10.1039/a701876b
PDF
Metal cation-exchanged montmorillonite (Mn+-mont)-catalysed aromatic alkylation with aldehydes and ketones
Jun-ichi Tateiwa Ei Hayama Takahiro Nishimura and Sakae Uemura
pg 1923; DOI:
10.1039/a701744h
PDF
Intramolecular Diels–Alder additions to 2-benzopyran-3-ones; anti-selectivity induced by the phenylsulfonyl group1
Edward J. Bush David W. Jones and Tracie C. L. M. Ryder
pg 1929; DOI:
10.1039/a701589e
PDF
Synthesis of 1,2,4-dioxazolidine derivatives by the ozonolysis of indenes in the presence of primary amines
Yoshihiro Ushigoe Syuzo Satake Araki Masuyama Masatomo Nojima and Kevin J. McCullough
pg 1939; DOI:
10.1039/a701572k
PDF
Oligomeric flavanoids. Part 26. Structure and synthesis of the first profisetinidins with epifisetinidol constituent units
Petrus J. Steynberg Jan P. Steynberg E. Vincent Brandt Daneel Ferreira and Richard W. Hemingway
pg 1943; DOI:
10.1039/a701334e
PDF
Automated synthesis of branched oligodeoxynucleotide analogues using arabino-uridine as branching nucleotide
Michael Meldgaard Nanna K. Nielsen Murray Bremner Ole S. Pedersen Carl Erik Olsen and Jesper Wengel
pg 1951; DOI:
10.1039/a701228d
PDF
Synthesis of 3,4-dibromo-2,2-bithiophene: a useful intermediate for 3,4-disubstituted 2,2-bithiophenes. X-Ray molecular structure of 3,4-dibromo-2,2-bithiophene
Luciano Antolini Francesca Goldoni Dario Iarossi Adele Mucci and Luisa Schenetti
pg 1957; DOI:
10.1039/a700811b
PDF
Synthesis of -lactones. Part 7.1 -Chloro- and ,-dichloro--lactones by aldolization of carbonyl compounds with lithium ester enolates derived from chlorinated phenyl alkanoates: an unusual course of the Darzens reaction
Christine Wedler Katharina Kleiner Egon Gründemann and Hans Schick
pg 1963; DOI:
10.1039/a700805h
PDF
Convenient and stereospecific homologation of N-fluorenylmethoxycarbonyl--amino acids to their -homologues
Antonella Leggio Angelo Liguori Antonio Procopio and Giovanni Sindona
pg 1969; DOI:
10.1039/a700731k
PDF
Synthesis of neoglycoproteins containing L-glycero--D- manno-heptopyranosyl-(14)- and -(15)-linked 3-deoxy--D-manno-oct-2- ulopyranosylonic acid (Kdo) phosphate determinants
Harald Sekljic Norbert Wimmer Andreas Hofinger Helmut Brade and Paul Kosma
pg 1973; DOI:
10.1039/a700497d
PDF
Three component aminoalkylation of aldehydes by functionalized organozinc compounds promoted by lithium perchlorate (LiClO4)
Mohammad R. Saidi Hamid R. Khalaji and Junes Ipaktschi
pg 1983; DOI:
10.1039/a700371d
PDF
Silyl enol ethers as new protecting groups for alkyl 4-halo-3-oxobutanoates; the preparation of pure (3-alkoxycarbonyl-2-oxopropyl)triphenylphosphonium salts
Cornelis M. Moorhoff
pg 1987; DOI:
10.1039/a700241f
PDF
Molecular engineering. Part 2.1 Influence of side-chain substituents in lariat-type upper-rim calix[4]crowns on their binding properties and the reversal of these
Hyejae Ihm Hyunjun Kim and Kyungsoo Paek
pg 1997; DOI:
10.1039/a700165g
PDF
Bicyclo[3.3.1]nonanes as synthetic intermediates. Part 21.1 Enantiodivergent synthesis of the cis,cis 2,6-disubstituted piperidin-3-ol chiral building block for alkaloid synthesis
Takefumi Momose Naoki Toyooka and Makoto Jin
pg 2005; DOI:
10.1039/a608490g
PDF

Issue 14


Synthesis and characterization of 2-methoxy-2H-azepines: the first isolation of 2-azanorcaradiene, the valence isomer of 3H-azepine
Kyosuke Satake Yuko Tawada Hideki Okamoto and Masaru Kimura
pg 2015; DOI:
10.1039/a703709k
PDF
First synthesis of sulfines by direct oxidation of xanthates
Eddie Marrière David Chevrie and Patrick Metzner
pg 2019; DOI:
10.1039/a703706f
PDF
New and efficient approach to the synthesis of pentacoordinate spirobicyclic phosphoranes
Hua Fu Guang-Zhong Tu Zhao-Long Li Yu-Fen Zhao and Ri-Qing Zhang
pg 2021; DOI:
10.1039/a702813j
PDF
Direct preparation of diacetals from 1,2-diketones and their use as 1,2-diol protecting groups
Achim Hense Steven V. Ley Helen M. I. Osborn Dafydd R. Owen Jean-François Poisson Stuart L. Warriner and Kieron E. Wesson
pg 2023; DOI:
10.1039/a702497e
PDF
Evidence for oxacarbenium ion intermediates in the Lewis acid promoted cleavage of spirocyclic dioxanes
Lee A. Newitt and Patrick G. Steel
pg 2033; DOI:
10.1039/a701764b
PDF
Synthesis of 19-hydroxy-1,19-cyclosteroids
John F. Templeton Weiyang Lin Yangzhi Ling Helena Majgier-Baranowska and Kirk Marat
pg 2037; DOI:
10.1039/a701570d
PDF
Biomimetic synthesis of a peptide antibiotic, gratisin
Makoto Tamaki Seiji Komiya Sadatoshi Akabori and Ichiro Muramatsu
pg 2045; DOI:
10.1039/a701537b
PDF
Synthesis of oligodeoxynucleotides containing 5-aminouracil and its N-acetyl derivative
Elisenda Ferrer Gitte Neubauer Matthias Mann and Ramon Eritja
pg 2051; DOI:
10.1039/a701371j
PDF
Synthesis of indoles and quinolones by sequential Wittig and Heck reactions
Elliot J. Latham and Stephen P. Stanforth
pg 2059; DOI:
10.1039/a701282i
PDF
In vitro biosynthesis of cadinanes by cell-free extracts of cultured cells of Heteroscyphus planus
Kensuke Nabeta Masaru Fujita Kaori Komuro Kinya Katayama and Toshihide Takasawa
pg 2065; DOI:
10.1039/a701145h
PDF
Thermolysis and CoII-tetraphenylporphyrin-catalysed decomposition of substituted cycloheptatriene endoperoxides: a new synthetic approach to substituted dihydrooxepines
M. Emin Sengül and Metin Balci
pg 2071; DOI:
10.1039/a701105i
PDF
1-Substituted 2-deoxyinosine analogues
Lorenzo De Napoli Anna Messere Daniela Montesarchio Gennaro Piccialli and Michela Varra
pg 2079; DOI:
10.1039/a700987i
PDF
Design, synthesis and pharmacological test of a quinoline based, nonpeptidic analogue of neurotensin(8–13)
Feng Hong Yuan-Ping Pang Bernadette Cusack and Elliott Richelson
pg 2083; DOI:
10.1039/a700894e
PDF
Homoproline homologation by enolate Claisen rearrangement or direct allylation: syntheses of (-)-trachelanthamidine, (-)-isoretronecanol and ()-turneforcidine
David W. Knight Andrew C. Share and Peter T. Gallagher
pg 2089; DOI:
10.1039/a700792b
PDF
Haem d1: stereoselective synthesis of the reduced form of its parent macrocycle using the original coupling strategy
Christopher J. Aucken Finian J. Leeper and Alan R. Battersby
pg 2099; DOI:
10.1039/a700652g
PDF
Haem d1: development of a new coupling procedure leading to the synthesis of isobacteriochlorins1
Richard L. Mackman Jason Micklefield Michael H. Block Finian J. Leeper and Alan R. Battersby
pg 2111; DOI:
10.1039/a700654c
PDF
Haem d1: stereoselective synthesis of the macrocycle to establish its absolute configuration as 2R,7R1
Jason Micklefield Marion Beckmann Richard L. Mackman Michael H. Block Finian J. Leeper and Alan R. Battersby
pg 2123; DOI:
10.1039/a700655a
PDF
Synthesis and pyrolytic behaviour of thiazolidin-2-one 1,1-dioxides
R. Alan Aitken David P. Armstrong Ronald H. B. Galt and Shaun T. E. Mesher
pg 2139; DOI:
10.1039/a700521k
PDF
Isolation and sequence analysis of the peptide antibiotics trichorzins PA from Trichoderma harzianum
Delphine Duval Sylvie Rebuffat Christophe Goulard Yann Prigent Michel Becchi and Bernard Bodo
pg 2147; DOI:
10.1039/a700244k
PDF
Ring-opening reactions of functionalized bicyclo[2.2.0]hexanes
M. Liliana Graziano M. Rosaria Iesce Flavio Cermola and Giuseppina Ialongo
pg 2155; DOI:
10.1039/a607507j
PDF

Issue 15


Chiral base-mediated asymmetric functionalisation of tricarbonylchromium(0) complexes of benzyl sulfides
Susan E. Gibson Peter Ham Gary R. Jefferson and Mark H. Smith
pg 2161; DOI:
10.1039/a704252c
PDF
Synthesis of new trialkylsilylmethyloxazinones via intramolecular trapping of -silyl carbocations by an N-Boc group
Sylvie Brocherieux-Lanoy Hamid Dhimane Jean-Christophe Poupon Corinne Vanucci and Gérard Lhommet
pg 2163; DOI:
10.1039/a703902f
PDF
Unusual condensation of 2-(2-dimethylaminovinyl)-1-benzopyran-4-one with dimethyl acetylenedicarboxylate: formation of 2,3-bis(methoxycarbonyl)xanthen-9-one
Chandra Kanta Ghosh Samita Bhattacharyya and Amarendra Patra
pg 2167; DOI:
10.1039/a703495d
PDF
Metal cation-exchanged montmorillonite(Mn+-Mont)-catalysed carbonyl-ene reactions
Jun-ichi Tateiwa Akihiro Kimura Masaaki Takasuka and Sakae Uemura
pg 2169; DOI:
10.1039/a702906c
PDF
An expeditious synthesis of chaetomellic anhydrides A and B, and analogues
Stéphane Poigny Michèle Guyot and Mohammad Samadi
pg 2175; DOI:
10.1039/a702668d
PDF
Total synthesis of (-)-slaframine from (2R,3S)-3-hydroxyproline
David W. Knight and A. William Sibley
pg 2179; DOI:
10.1039/a701878i
PDF
Synthesis and some reactions of N-amino-2-methoxy-1-azaazulenium salt: leading to 3,3a-diazacyclopent[a]azulene and 2a,3-diazabenz[cd]azulene systems
Abe Noritaka Kunihiko Odagiri and Akikazu Kakehi
pg 2189; DOI:
10.1039/a701793f
PDF
Synthesis of pyrrolizin-3-ones by flash vacuum pyrolysis of pyrrol-2-ylmethylidene Meldrums acid derivatives and 3-(pyrrol-2-yl)propenoic esters
Shirley E. Campbell Murray C. Comer Paul A. Derbyshire Xavier L. M. Despinoy Hamish McNab Roderick Morrison Craig C. Sommerville and Craig Thornley
pg 2195; DOI:
10.1039/a701749i
PDF
New synthetic routes to pyrrolo-[1,2-a]- and -[1,2-c]-imidazol-5-ones by flash vacuum pyrolysis
Hamish McNab and Craig Thornley
pg 2203; DOI:
10.1039/a701751k
PDF
Synthesis and structural characteristics of novel 5H-thiazolo[2,3-d][1,5]benzothiazepine derivatives
Giuseppe Bruno Alba Chimirri Rosaria Gitto Silvana Grasso Francesco Nicolò Rosario Scopelliti and Maria Zappalà
pg 2211; DOI:
10.1039/a701539i
PDF
Abnormal products in the Bischler–Napieralski isoquinoline synthesis
Satoshi Doi Naohiro Shirai and Yoshiro Sato
pg 2217; DOI:
10.1039/a701332i
PDF
Approaches to pseudopeptidic ergopeptines. Part 3.1 Consequences of the incorporation of an -azaphenylalanine residue into the ergotamine oxa-cyclolic system
Anna Calcagni Gino Lucente Grazia Luisi Francesco Pinnen Domenico Rossi and Enrico Gavuzzo
pg 2223; DOI:
10.1039/a701230f
PDF
Approaches to 1,1-disubstituted cinnolin-3-ylio oxides: synthesis and reactivity of a new class of heterocyclic betaines
Vicente J. Arán Juan L. Asensio José Molina Pilar Muñoz José R. Ruiz and Manfred Stud
pg 2229; DOI:
10.1039/a701103b
PDF
Synthesis and biological activity of side-chain analogues of ecdysone and 20-hydroxyecdysone
Patrick G. Roussel Vladimir Sik Nicholas J. Turner and Laurence N. Dinan
pg 2237; DOI:
10.1039/a700986k
PDF
Further reactions of furans with trithiazyl trichloride; mechanistic considerations
Charles W. Rees and Tai-Yuen Yue
pg 2247; DOI:
10.1039/a700488e
PDF
Synthesis of enantiomerically pure (1R,2R)- and (1S,2S)-2-alkyl-1-phenylsulfonylcyclopropanes using Bakers yeast
Rikuhei Tanikaga Noriaki Shibata and Takamitsu Yoneda
pg 2253; DOI:
10.1039/a700160f
PDF

Issue 16


Novel ring transformation of nitropyrimidinone; synthetic equivalent of -nitroformylacetic acid
Nagatoshi Nishiwaki Hui-Ping Wang Kengo Matsuo Yasuo Tohda and Masahiro Ariga
pg 2261; DOI:
10.1039/a704354f
PDF
Novel synthesis of substituted 4-hydroxy-2,2:6,2-terpyridines
Reza-Ali Fallahpour and Edwin C. Constable
pg 2263; DOI:
10.1039/a704295g
PDF
Catalytic asymmetric epoxidation with a chiral ruthenium porphyrin and N-oxides
Albrecht Berkessel and Matthias Frauenkron
pg 2265; DOI:
10.1039/a704275b
PDF
First diastereoselective [3+2] cycloaddition of chiral non-racemic alkenyl Fischer carbene complexes with diazomethane derivatives
José Barluenga Félix Fernández-Marí Argimiro L. Viado Enrique Aguilar and Bernardo Olano
pg 2267; DOI:
10.1039/a704228k
PDF
Towards a synthesis of C3-tribenzohemifullerene, a C42H18 fragment of [60]fullerene
Goverdhan Mehta Gautam Panda Shailesh R. Shah and Ajit C. Kunwar
pg 2269; DOI:
10.1039/a702911j
PDF
Butoxycarbonylation of aryl halides catalyzed by a silica-supported poly[3-(2-cyanoethylsulfanyl)propylsiloxane palladium] complex
Ming-Zhong Cai Cai-Sheng Song and Xian Huang
pg 2273; DOI:
10.1039/a702085f
PDF
Remarkable acceleration of a lipase-catalyzed reaction by a thiacrown ether additive: buffer-free highly regioselective partial hydrolysis of 4-acetoxy-2-methylbut-2-enyl acetate
Toshiyuki Itoh Koichi Mitsukura Kunihiro Kaihatsu Hiroki Hamada Yumiko Takagi and Hiroshi Tsukube
pg 2275; DOI:
10.1039/a702894f
PDF
Chromium(II)-mediated synthesis of vinylbis(silanes) from aldehydes and a study of acid- and base-induced reactions of the derived epoxybis(silanes): a synthesis of acylsilanes
David M. Hodgson Paul J. Comina and Michael G. B. Drew
pg 2279; DOI:
10.1039/a702722b
PDF
Sulfur-controlled 6-exo aryl radical cyclisation of N-ethenyl-2-(2-bromophenyl)acetamides: synthesis of ()-tetrahydropalmatine and saulatine
Hiroyuki Ishibashi Hirotaka Kawanami Hiroko Nakagawa and Masazumi Ikeda
pg 2291; DOI:
10.1039/a702307c
PDF
Synthesis of fused 1,2,5-triazepine-1,5-diones and some N2- and N3-substituted derivatives: potential conformational mimetics for cis-peptidyl prolinamides1
Morag M. Lenman Arwel Lewis and David Gani
pg 2297; DOI:
10.1039/a702107k
PDF
Direct C-11 functionalisation of anatoxin-a. Application to the synthesis of new ligand-based structural probes
Nicholas A. Magnus Laurent Ducry Valérie Rolland Susan Wonnacott and Timothy Gallagher
pg 2313; DOI:
10.1039/a702087b
PDF
Oxidative rearrangement and cyclisation of N-substituted amidines using iodine(III) reagents and the influence of leaving group on mode of reaction
Christopher A. Ramsden and Helen L. Rose
pg 2319; DOI:
10.1039/a702025b
PDF
The synthesis of antioxidants showing selective affinity for low density lipoproteins
David W. Brown Mary F. Mahon Aleyamma Ninan and Malcolm Sainsbury
pg 2329; DOI:
10.1039/a701948c
PDF
Some single electron-transfer reactions of arylimines
David W. Brown Monika Lindquist Mary F. Mahon Bengt Malm Göran N. Nilsson Aleyamma Ninan Malcolm Sainsbury and Christer Westerlund
pg 2337; DOI:
10.1039/a701947e
PDF
Zinc(II)-catalysed asymmetric hetero-Diels–Alder reactions of conjugated dienes with glyoxylate
Sulan Yao Mogens Johannsen and Karl Anker Jørgensen
pg 2345; DOI:
10.1039/a701882g
PDF
Lignin–ferulate cross-links in grasses. Part 4.1–3 Incorporation of 5–5-coupled dehydrodiferulate into synthetic lignin
Stéphane Quideau and John Ralph
pg 2351; DOI:
10.1039/a701808h
PDF
Synthesis of glycopeptide sequences of repeating units of the mucins MUC 2 and MUC 3 containing oligosaccharide side-chains with core 1, core 2, core 3, core 4 and core 6 structure
Nathalie Mathieux Hans Paulsen Morten Meldal and Klaus Bock
pg 2359; DOI:
10.1039/a701742a
PDF
Photochemical substitution of halogenopyrrole derivatives
Maurizio DAuria Eliana De Luca Giacomo Mauriello Rocco Racioppi and Giancarlo Sleiter
pg 2369; DOI:
10.1039/a701674c
PDF
Preparation of fluorinated galactosyl nucleoside diphosphates to study the mechanism of the enzyme galactopyranose mutase
Andrew Burton Paul Wyatt and Geert-Jan Boons
pg 2375; DOI:
10.1039/a701630a
PDF
Transglycosylation activity of Bacillus 1,3-1,4--D-glucan 4-glucanohydrolases. Enzymic synthesis of alternate 1,3,-1,4--D-glucooligosaccharides
Josep-Lluís Viladot Vincent Moreau Antoni Planas and Hugues Driguez
pg 2383; DOI:
10.1039/a701431g
PDF
Improved, gram scale synthesis of N,O,O-triacetyl-erythro- and threo-C18-sphingosines from serine
Alessondro Dondoni Daniela Perrone and Elisa Turturici
pg 2389; DOI:
10.1039/a701391d
PDF
Acid-catalyzed rearrangements of flavan-4-phloroglucinol derivatives to novel 6-hydroxyphenyl-6a,11b-dihydro-6H-[1]benzofuro[2,3-c] chromenes and hydroxyphenyl-3,2-spirobi[dihydro[1]benzofurans]
Petrus J. Steynberg Jan P. Steynberg Richard W. Hemingway Daneel Ferreira and G. Wayne McGraw
pg 2395; DOI:
10.1039/a700889i
PDF
Synthesis of the marine dibromooxoindoline convolutamydine C
Soyfur Miah Christopher J. Moody Ian C. Richards and Alexandra M. Z. Slawin
pg 2405; DOI:
10.1039/a700683g
PDF
Studies towards the synthesis of diazonamide A. Unexpected formation of a 3,4-bridged indole
Christopher J. Moody Kevin J. Doyle Mark C. Elliott and Timothy J. Mowlem
pg 2413; DOI:
10.1039/a700684e
PDF
Reaction of lactim ethers and lactim sulfides with electrophiles: attack at nitrogen followed by ring-opening under neutral conditions
Mariappan Anbazhagan Arun N. Dixit and Srinivasachari Rajappa
pg 2421; DOI:
10.1039/a700523g
PDF
The solid-state diastereoselective formation of oxazolidines
Natalya S. Khruscheva Nikolay M. Loim Viatcheslav I. Sokolov and V. D. Makhaev
pg 2425; DOI:
10.1039/a700246g
PDF
Photogeneration of amines from -keto carbamates: design and preparation of photoactive compounds
James F. Cameron C. Grant Willson and Jean M. J. Fréchet
pg 2429; DOI:
10.1039/a602018f
PDF
Synthesis of L-selenocystine, L-[77Se]selenocystine and L-tellurocystine
Emily M. Stocking Jessie N. Schwarz Hans Senn Michael Salzmann and Louis A. Silks
pg 2443; DOI:
10.1039/a600180g
PDF

Issue 17


Nickel-catalysed cross-coupling reactions of aryl halides with organostannanes
Eiji Shirakawa Kenji Yamasaki and Tamejiro Hiyama
pg 2449; DOI:
10.1039/a705078j
PDF
Development of arylhydrazines and diphenyl arylhydrazidophosphates as photo-induced DNA-cleaving agents
Jih Ru Hwu Chii Shyang Yau Fu Yuan Tsai and Shwu-Chen Tsay
pg 2451; DOI:
10.1039/a704706a
PDF
Insertion of ethyl diazoacetate into N–H and S–H bonds catalyzed by ruthenium porphyrin complexes
Erwan Galardon Paul Le Maux and Gérard Simonneaux
pg 2455; DOI:
10.1039/a704687a
PDF
Highly diastereoselective synthesis of densely functionalized cyclopentanoids by intramolecular azomethine imine cycloadditions in sugar templates
John K. Gallos Alexandros E. Koumbis and Nicolaos E. Apostolakis
pg 2457; DOI:
10.1039/a704207h
PDF
Synthesis of cyclitols fused with a furoxan ring from alditols by intramolecular nitrile oxide dimerization
John K. Gallos Theoharis V. Koftis Vassiliki I. Karamitrou and Alexandros E. Koumbis
pg 2461; DOI:
10.1039/a704208f
PDF
Synthesis of functionalised unsymmetrical diaryliodonium salts
Aneela Shah Victor W. Pike and David A. Widdowson
pg 2463; DOI:
10.1039/a704062h
PDF
Glycosylation of silybin
Vladimír Ken Jií Kubisch Petr Sedmera Petr Halada Vra Pikrylová Alexandr Jegorov Ladislav Cvak Rolf Gebhardt Jitka Ulrichová and Vilím imánek
pg 2467; DOI:
10.1039/a703283h
PDF
Synthesis of a cis-conformationally restricted peptide bond isostere and its application to the inhibition of the HIV-1 protease
Andrew D. Abell and Glenn J. Foulds
pg 2475; DOI:
10.1039/a702458d
PDF
Synthesis of fused furans by gas-phase pyrolysis of 2-allyloxyarylpropenoic esters1
Michael Black J. I. G. Cadogan Hamish McNab Andrew D. MacPherson V. Peter Roddam Carol Smith and Helen R. Swenson
pg 2483; DOI:
10.1039/a702451g
PDF
Design and preparation of serine–threonine protein phosphatase inhibitors based upon the nodularin and microcystin toxin structures: Part 1. Evaluation of key inhibitory features and synthesis of a rationally stripped-down nodularin macrocycle
Amit P. Mehrotra Kerri L. Webster and David Gani
pg 2495; DOI:
10.1039/a702407j
PDF
Design and preparation of serine–threonine protein phosphatase inhibitors based upon the nodularin and microcystin toxin structures: Part 2.1 Synthesis of a functionalised nodularin macrocycle and a stripped-down microcystin macrocycle
Antony B. Maude Amit P. Mehrotra and David Gani
pg 2513; DOI:
10.1039/a702410j
PDF
Structures of a new type of yellow pigments, falconensones A and B, from Emericella falconensis
Nobuko Ogasawara Reiko Mizuno and Ken-ichi Kawai
pg 2527; DOI:
10.1039/a701277b
PDF
Asymmetric total synthesis of (+)-carbocyclic uracil polyoxin C
Varinder K. Aggarwal and Nuno Monteiro
pg 2531; DOI:
10.1039/a702323e
PDF
Dialkyl phosphonates and tetraalkyl bis(phosphonate)s from the decomposition of quasi-phosphonium ylidic phosphonates in aqueous conditions
D. Vaughan Griffiths Khalku Karim and Jayne E. Harris
pg 2539; DOI:
10.1039/a702258a
PDF
Reactions of carbene intermediates from the reaction of trialkyl phosphites with dialkyl benzoylphosphonates: preparation and reactions of dimethyl 2-(N-tert-butyl-N-methylamino) benzoylphosphonate and dimethyl 2-(methylamino)benzoylphosphonate
D. Vaughan Griffiths Jayne E. Harris and Belinda J. Whitehead
pg 2545; DOI:
10.1039/a701147d
PDF
Stereoselective synthesis of 4-alkoxy-3-methylidenealkanols using reactions between 2-(1-alkoxyalkyl)propenylstannanes and aldehydes: X-ray crystal structure of (1R,4R)-3-methylidene-1-(4-nitrophenyl)pentane-1,4-diol
Pedro Almendros Michelangelo Gruttadauria Madeleine Helliwell and Eric J. Thomas
pg 2549; DOI:
10.1039/a702256e
PDF
On the stereoselectivity of reactions of alkoxyallylstannanes and alkoxy aldehydes
Pedro Almendros and Eric J. Thomas
pg 2561; DOI:
10.1039/a702257c
PDF
Synthesis and utilisation of 6-aminotetrahydrobenzo[7]annulenes
David A. Learmonth George R. Proctor and David I. C. Scopes
pg 2569; DOI:
10.1039/a702212c
PDF
Palladium-catalysed heteroannulation of vinylic compounds: a highly convenient method for the synthesis of N-aryl-1,2,3,4-tetrahydro-1-oxoisoquinoline-3-carboxylic acids
Jyan S. Mahanty Mahuya De and Nitya G. Kundu
pg 2577; DOI:
10.1039/a702032e
PDF
Chelation of diamine ligands to zinc porphyrin monolayers amide-linked to glass
Duncan W. J. McCallien Paul L. Burn and Harry L. Anderson
pg 2581; DOI:
10.1039/a701968h
PDF
Synthesis of 2-thio-uridine and -cytidine derivatives as potential inhibitors of ribonucleoside diphosphate reductase: thionitrites, disulfides and 2-thiouridine 5-diphosphate
Loïc Le Hir de Fallois Jean-Luc Décout and Marc Fontecave
pg 2587; DOI:
10.1039/a701820g
PDF
Reaction of trithiazyl trichloride with alkenes and alkynes
Xiao-Guang Duan Xiao-Lan Duan Charles W. Rees and Tai-Yuen Yue
pg 2597; DOI:
10.1039/a701818e
PDF
Metal-assisted reactions. Part 27.1 3-Benzyloxy-1,2-benzisothiazole 1,1-dioxide: an unusual ether linkage that does not permit heterogeneous catalytic hydrogenolysis
Amadeu F. Brigas Pedro M. Goncalves and Robert A. W. Johnstone
pg 2603; DOI:
10.1039/a701672g
PDF
Atroposelectivity in the reactions of ortholithiated aromatic tertiary amides with aldehydes
Peter Bowles Jonathan Clayden Madeleine Helliwell Catherine McCarthy Matthew Tomkinson and Neil Westlund
pg 2607; DOI:
10.1039/a701671i
PDF
Synthesis and desaturation of monofluorinated fatty acids1
Peter H. Buist Kostas A. Alexopoulos Behnaz Behrouzian Brian Dawson and Bruce Black
pg 2617; DOI:
10.1039/a701571b
PDF
Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 10.1 Generation of 2-methylstyrylalkynes and their thermal cyclisation to 2-alkenylnaphthalenes
R. Alan Aitken Christine Boeters and John J. Morrison
pg 2625; DOI:
10.1039/a701427i
PDF
Chiral oximes in asymmetric synthesis. Part 2.1 Addition of butyllithium to benzaldehyde O-(1-phenylalkyl)oximes
Peter T. Gallagher James C. A. Hunt Andrew P. Lightfoot and Christopher J. Moody
pg 2633; DOI:
10.1039/a700984d
PDF
Synthesis of 1,2-fused indoles by radical cyclisation1
Christopher J. Moody and Claire L. Norton
pg 2639; DOI:
10.1039/a700985b
PDF
Asymmetric dihydroxylation of allylic phosphine oxides
Adam Nelson and Stuart Warren
pg 2645; DOI:
10.1039/a700374i
PDF
Chemistry of 5-oxodihydroisoxazoles. Part 17.1 Acylation of 5-oxodihydroisoxazoles
Rolf H. Prager Jason A. Smith Ben Weber and Craig M. Williams
pg 2659; DOI:
10.1039/a700133i
PDF
Chemistry of 5-oxodihydroisoxazoles. Part 18.1 Synthesis of oxazoles by the photolysis and pyrolysis of 2-acyl-5-oxo-2,5-dihydroisoxazoles
Rolf H. Prager Jason A. Smith Ben Weber and Craig M. Williams
pg 2665; DOI:
10.1039/a700134g
PDF
The chemistry of 5-oxodihydroisoxazoles. Part 19.1 The synthesis and photolysis of N-thioacylisoxazol-5(2H)-ones
Rolf H. Prager Max R. Taylor and Craig M. Williams
pg 2673; DOI:
10.1039/a700646b
PDF

Issue 18


Sodium hydroxide-promoted reaction of 1-substituted 2,3,3-trifluoroprop-1-enyl toluene-p-sulfonates with alcohols. First efficient and convenient access to -fluoro-,-dialkoxy ketones
Kazumasa Funabiki Chisato Suzuki Seizi Takamoto Masaki Matsui and Katsuyoshi Shibata
pg 2679; DOI:
10.1039/a705495e
PDF
Phosphabenzene–rhodium catalysts for the efficient hydroformylation of terminal and internal olefins
Bernhard Breit Roland Winde and Klaus Harms
pg 2681; DOI:
10.1039/a705249i
PDF
Studies in sulfur heterocycles. Part 13.1 An expedient synthesis of 7-hydroxybenzo[b]thiophene and its 2- and 3-substituted derivatives
Subhendu Sekhar Samanta Sukhen Chandra Ghosh and Asish De
pg 2683; DOI:
10.1039/a705119k
PDF
Investigations into nicotinic acetylcholine receptor (nAChR) antagonists: synthesis of a sub-unit of methyllycaconitine
Lynn C. Baillie John R. Bearder John A. Sherringham and Donald A. Whiting
pg 2687; DOI:
10.1039/a704447j
PDF
Phenylselenotris(trimethylsilyl)silane and phenyltellurotris(trimethylsilyl)silane: versatile reagents for the preparation of phenylseleno- and phenyltelluro-formates
Carl H. Schiesser and Melissa A. Skidmore
pg 2689; DOI:
10.1039/a704402j
PDF
Synthesis of 2,3,4-triphenyl-3-azabicyclo[3.2.0]hepta-1,4-diene and its novel reaction with dimethyl acetylenedicarboxylate
Kiyoshi Matsumoto Sadahito Goto Naoto Hayashi Takane Uchida and Akikazu Kakehi
pg 2691; DOI:
10.1039/a704090c
PDF
One-step syntheses of pyrrolo- and indolo-1,2,5-thiadiazoles and pyrrolobis[1,2,5]thiadiazoles
Xiao-Guang Duan and Charles W. Rees
pg 2695; DOI:
10.1039/a703133e
PDF
[11C]Carbon monoxide in the palladium-mediated synthesis of 11C-labelled ketones
Pelle Lidström Tor Kihlberg and Bengt Långström
pg 2701; DOI:
10.1039/a703062b
PDF
Applications of the spiroannulation of tetralins with alkynes; towards new anti-estrogenic compounds
F. Thomas Boyle Owen Hares Zbigniew S. Matusiak Warren Li and Donald A. Whiting
pg 2707; DOI:
10.1039/a702992f
PDF
Carotenoids and related polyenes. Part 4.1 Synthesis of carotenoid analogues containing a conjugated carbonyl group and their fluorescence properties
Yumiko Yamano Mamoru Mimuro and Masayoshi Ito
pg 2713; DOI:
10.1039/a702815f
PDF
Studies on the reactivity of azetidin-2-ones in phosphate buffer
Nicholas J. Westwood Christopher J. Schofield and Timothy D. W. Claridge
pg 2725; DOI:
10.1039/a702673k
PDF
Total synthesis of C31-methyl ketone apocarotenoids. Part 4. First total synthesis of (3S,5R,6R)-paracentrone
Jarle André Haugan
pg 2731; DOI:
10.1039/a702545i
PDF
Antitumour polycyclic acridines. Part 1. Synthesis of 7H-pyrido- and 8H-quino-[4,3,2-kl]acridines by Graebe–Ullmann thermolysis of 9-(1,2,3-triazol-1-yl)acridines: application of differential scanning calorimetry to predict optimum cyclisation conditions
Damien J. Hagan Elena Giménez-Arnau Carl H. Schwalbe and Malcolm F. G. Stevens
pg 2739; DOI:
10.1039/a702299i
PDF
Regioselective aryl radical cyclisation. Part 2.1 Synthesis of octahydro-1H-dibenzo[a,d]cycloheptenes through 7-endo ring closure
Ajit K. Ghosh Jayanta K. Mukhopadhyaya and Usha Ranjan Ghatak
pg 2747; DOI:
10.1039/a702253k
PDF
Enantioselective addition of dialkylzincs to N-diphenylphosphinylimines using polymer-supported N,N-dialkylnorephedrines as chiral ligands
Takefumi Suzuki Takanori Shibata and Kenso Soai
pg 2757; DOI:
10.1039/a702139i
PDF
Synthesis, structure and reactions of uridine 2-C,3-O--butyrolactone: versatile intermediate for the synthesis of 2-C-branched nucleosides
Anthony J. Lawrence John B. J. Pavey Mai-Yee Chan Robin A. Fairhurst Stephen P. Collingwood Julie Fisher Richard Cosstick and Ian A. ONeil
pg 2761; DOI:
10.1039/a702088k
PDF
Parasite glycoconjugates. Part 7.1 Synthesis of further substrate analogues of early intermediates in the biosynthetic pathway of glycosylphosphatidylinositol membrane anchors
Arthur Crossman Jr John S. Brimacombe and Michael A. J. Ferguson
pg 2769; DOI:
10.1039/a701881i
PDF
Stereoselective construction of vicinal diamines. Part 3.1 Routes to the benz[ f ]indeno[1,7-bc] azepine and benz[e]indeno[2,1-b][1,4]diazepine ring systems
Barry S. Orlek and Eleanor A. Crowe
pg 2775; DOI:
10.1039/a701762f
PDF
Protection of the guanine residue during synthesis of 2-O-alkylguanosine derivatives
Morten Grøtli Mark Douglas Barbro Beijer Ramon Güimil García Ramon Eritja and Brian Sproat
pg 2779; DOI:
10.1039/a700813i
PDF
Design, synthesis and evaluation of a novel series of spiroketals based on the structure of the antibacterial gyrase inhibitor novobiocin
William Bell Michael H. Block Calum Cook J. Andrew Grant and David Timms
pg 2789; DOI:
10.1039/a700647k
PDF

Issue 19


Rapid access to rare natural pyranosides using 1,2-diacetal protected intermediates
Steven V. Ley Dafydd R. Owen and Kieron E. Wesson
pg 2805; DOI:
10.1039/a705360f
PDF
2-Aminobuta-1,3-dienes as annulation reagents for 4-quinolones and benzothiopyran-4-ones: an attractive route for the highly diastereoselective synthesis of acridine- and thioxanthene-derivatives
Uwe Beifuss and Michael Taraschewski
pg 2807; DOI:
10.1039/a704289b
PDF
Dimethylsulfonium fluoren-9-ide: solution structure and dynamic behaviour of a semi-stabilised sulfonium ylide
Varinder K. Aggarwal Steffen Schade and Brian Taylor
pg 2811; DOI:
10.1039/a704010e
PDF
Palladium-catalysed heteroannulation with acetylenic compounds: synthesis of benzofurans1
Nitya G. Kundu Manojit Pal Jyan S. Mahanty and Mahuya De
pg 2815; DOI:
10.1039/a703305b
PDF
Ketone homologation to produce -methoxyketones: application to conduritol synthesis
Neil Phillipson Michael S. Anson John G. Montana and Richard J. K. Taylor
pg 2821; DOI:
10.1039/a703073h
PDF
Reaction of trithiazyl trichloride with active methylene compounds
Xiao-Guang Duan Xiao-Lan Duan and Charles W. Rees
pg 2831; DOI:
10.1039/a703033i
PDF
Rapid synthesis of aliphatic amides by reaction of carboxylic acids, Grignard reagent and amines: application to the preparation of [11C]amides
Catherine Aubert Cécile Huard-Perrio and Marie-Claire Lasne
pg 2837; DOI:
10.1039/a702897k
PDF
Palladium-catalyzed chemoselective intramolecular cyclization of bromoanilinoalkenenitriles
Chau-Chen Yang Huo-Mu Tai and Pei-Jiun Sun
pg 2843; DOI:
10.1039/a702710i
PDF
Synthesis and conformational analysis of extended calix[4]arenes and a doubly bridged bis-calix[4]arene
Mikkel Jørgensen Mogens Larsen Peter Sommer-Larsen Walter Batsberg Petersen and Hanne Eggert
pg 2851; DOI:
10.1039/a702610b
PDF
Efficient selective synthesis of 2-substituted indoles from complex-base-promoted arynic cyclisations
Catherine Kuehm-Caubère Ivan Rodriguez Bruno Pfeiffer Pierre Renard and Paul Caubère
pg 2857; DOI:
10.1039/a702548c
PDF
Aqueous [6+4] cycloadditions of tropone with 1-(glucopyranosyloxy)buta-1,3-diene
André Lubineau Giliane Bouchain and Yves Queneau
pg 2863; DOI:
10.1039/a702447i
PDF
Unsaturated macrocyclic lactone synthesis via catalytic ring-closing metathesis1
Konstantinos E. Litinas and Basil E. Salteris
pg 2869; DOI:
10.1039/a702353g
PDF
Synthesis of chiral and achiral analogues of ambroxol via palladium-catalysed reactions
Anna L. E. Larsson Roberto G. P. Gatti and Jan-E. Bäckvall
pg 2873; DOI:
10.1039/a702141k
PDF
Furan-2(3H)- and -2(5H)-ones. Part 8.1 Conformation and di--methane reactivity of the 4,7-disubstituted tetrahydroisobenzofuran-1-one system: a mechanistic and exploratory study
Osamu Muraoka Genzoh Tanabe Emi Yamamoto Masaru Ono Toshie Minematsu and Takayoshi Kimura
pg 2879; DOI:
10.1039/a702108i
PDF
Synthesis and application of ligands for the asymmetric addition of organolithium reagents to imines
Catrin A. Jones Iwan G. Jones Mushtaq Mulla Michael North and Lucia Sartori
pg 2891; DOI:
10.1039/a702028g
PDF
Fullerene tectonics. Part 1. A programmed precursor to C60
M. John Plater
pg 2897; DOI:
10.1039/a701915g
PDF
Fullerene tectonics. Part 2.1 Synthesis and pyrolysis of halogenated benzo[c]phenanthrenes
M. John Plater
pg 2903; DOI:
10.1039/a701916e
PDF
Use of model cell membranes to demonstrate templated binding of vancomycin group antibiotics
Andrew C. Try Gary J. Sharman Robert J. Dancer Ben Bardsley Richard M. H. Entress and Dudley H. Williams
pg 2911; DOI:
10.1039/a701880k
PDF
Ring expansions of N-methyl-1,2,5-oxadiazolium and 1,2,3-triazolium perchlorate salts with bases to six-membered azines: direct detection of an addition intermediate in an addition–elimination mechanism and a degradation of 1,2,5-oxadiazolium salts to -cyano nitrones
Richard N. Butler Elaine C. McKenna John M. McMahon Karen M. Daly Desmond Cunningham and Patrick McArdle
pg 2919; DOI:
10.1039/a701233k
PDF
Regioselective synthesis of 6-substituted 2-hydroxybenzaldehyde: efficient synthesis of the immunomodulator tucaresol and related analogues
Boulos Zacharie Giorgio Attardo Nancy Barriault and Christopher Penney
pg 2925; DOI:
10.1039/a701102d
PDF
Rapid synthesis of polyester dendrimers
Zhishan Bo Xi Zhang Changmei Zhang Zhiqiang Wang Meilin Yang Jiacong Shen and Yiping Ji
pg 2931; DOI:
10.1039/a700841d
PDF
Simple synthetic entries into the tricyclo[5.3.1.13,9]dodecane and 8-oxatetracyclo[5.4.1.13,10.05,9]tridecane ring systems
Weimin Yue Roger Bishop Marcia L. Scudder and Donald C. Craig
pg 2937; DOI:
10.1039/a607710b
PDF

Issue 20


Convenient synthesis of cytotoxic (11E)-13-hydroxy-10-oxooctadec-11-enoic acid from undec-10-enoic acid
Junzo Nokami Masahiro Osafune Kazuhiro Shiraishi Shin-ichi Sumida and Nobuyuki Imai
pg 2947; DOI:
10.1039/a706245a
PDF
Chelation controlled cis-selective acylation of 2-(alkoxycarbonyl)cyclopentylzinc iodides
Morio Asaoka Akiko Kosaka Michiko Tanaka Tsuyoshi Ueda Takashi Houkawa and Hisashi Takei
pg 2949; DOI:
10.1039/a705554d
PDF
N-Alkylation and [2,3]-sigmatropic rearrangement of N-allyl -amino esters
Iain Coldham Mark L. Middleton and Philip L. Taylor
pg 2951; DOI:
10.1039/a705550a
PDF
Novel stereoselective synthesis of 1,3-dienyl selenides by palladium–copper cocatalyzed cross coupling reactions of (E)--selanylvinylstannanes
Yun Ma and Xian Huang
pg 2953; DOI:
10.1039/a703663i
PDF
A novel, chiral Lewis acid-induced enantioselective hetero Diels–Alder reaction of a thiabutadiene
Takao Saito Kayoko Takekawa Jun-ichi Nishimura and Mikako Kawamura
pg 2957; DOI:
10.1039/a703590j
PDF
Structural elucidation of trichotetronines: polyketides possessing a bicyclo[2.2.2]octane skeleton with a tetronic acid moiety isolated from Trichoderma sp.
Osamu Shirota Vibha Pathak Chowdhury Faiz Hossain Setsuko Sekita Kosuke Takatori and Motoyoshi Satake
pg 2961; DOI:
10.1039/a704963c
PDF
Ozone-mediated nitration of adamantane and derivatives with nitrogen dioxide: selectivity in the hydrogen abstraction by nitrogen trioxide and subsequent coupling of the resulting carbon radicals with nitrogen dioxide1
Hitomi Suzuki and Nobuaki Nonoyama
pg 2965; DOI:
10.1039/a704419d
PDF
Synthesis of 5,6-dihydropyrrolo[2,1-a]isoquinolines by rearrangement of 5-methyleneisoxazolidines generated from 1,3-dipolar cycloaddition of 3,4-dihydroisoquinoline N-oxides with allenes: a novel consecutive rearrangement to fused-ring pyrrole derivatives
Bao-Xiang Zhao and Shoji Eguchi
pg 2973; DOI:
10.1039/a704066k
PDF
Photocyclization of 2-(alkylthio)ethyl benzoylacetates via remote proton transfer following charge-transfer interaction between excited ketone carbonyl and thioether chromophore
Yuko Yamazaki Toyoharu Miyagawa and Tadashi Hasegawa
pg 2979; DOI:
10.1039/a703825i
PDF
Design, synthesis and antioxidant properties of ovothiol-derived 4-mercaptoimidazoles
Vincent Zoete Fabrice Bailly Jean-Pierre Catteau and Jean-Luc Bernier
pg 2983; DOI:
10.1039/a703741d
PDF
Displacement of bridgehead sulfonate esters with organometallic reagents: synthesis of 13-alkylated gibberellins
Martin Penny Susan M. Westaway and Christine L. Willis
pg 2989; DOI:
10.1039/a703587j
PDF
Design, synthesis and pharmacological evaluation of active pyrrole based, nonpeptidic analogues of neurotensin(8-13)
Feng Hong Javid Zaidi Yuan-Ping Pang Bernadette Cusack and Elliott Richelson
pg 2997; DOI:
10.1039/a703319b
PDF
Azabicyclo[3.2.0]heptan-7-ones (carbapenams) from pyrrole
Thomas L. Gilchrist Américo Lemos and Carol J. Ottaway
pg 3005; DOI:
10.1039/a703170j
PDF
Rearrangement of cis- and trans-1-methyl-2-(2-thienyl)pyrrolidinium 1-methylides in a non-basic medium
Nobuhiko Kawanishi Kazuhiko Fujiwara Naohiro Shirai Yoshiro Sato Keiichiro Hatano and Yukihisa Kurono
pg 3013; DOI:
10.1039/a703068a
PDF
C-Glycoside phosphoramidite building block for versatile functionalization of oligodeoxyribonucleotides
Jari Hovinen and Harri Salo
pg 3017; DOI:
10.1039/a703059b
PDF
v-Triazolines. Part 38.1 New synthesis of 4-aminoquinazolines and 6-aminopurines
Emanuela Erba and Daniela Sporchia
pg 3021; DOI:
10.1039/a703023a
PDF
Benzoxepine formation by the 1,7 electrocyclisation of diene-conjugated carbonyl ylides: studies on relative rates of cyclisation via intramolecular competition reactions
Donal F. OShea and John T. Sharp
pg 3025; DOI:
10.1039/a702962d
PDF
Convenient synthesis of 2-alkynyl-cyclopropanes and -oxiranes
Mitsuhiro Yoshimatsu Satoshi Gotoh Etsuko Gotoh Genzoh Tanabe and Osamu Muraoka
pg 3035; DOI:
10.1039/a702895d
PDF
Influence of a 2-fluoro substituent on diastereoselectivity in the 1,3-dipolar cycloadditions of nitrones
Masataka Ihara Yuko Tanaka Nobuyuki Takahashi Yuji Tokunaga and Keiichiro Fukumoto
pg 3043; DOI:
10.1039/a702810e
PDF
First synthesis of ortho-trifluoromethylated aryl triflates
Feng-Ling Qing Junfa Fan Hong-Bin Sun and Xiang-Jun Yue
pg 3053; DOI:
10.1039/a702607b
PDF
Preparation of chiral tricarbonyl arene thiol chromium and its application to asymmetric ring opening of meso-epoxides
Shin-ichi Fukuzawa Hirohisa Kato Makoto Ohtaguchi Yuki Hayashi and Hiroshi Yamazaki
pg 3059; DOI:
10.1039/a702406a
PDF
Synthesis of functionalised cyclic nitrones via regioselective and unusual [3+2] cycloadditions of -nitrosostyrenes with 1,3-diazabuta-1,3-dienes and imines
Arun K. Sharma Sujit N. Mazumdar and Mohinder P. Mahajan
pg 3065; DOI:
10.1039/a702254i
PDF
Aggregative activation in heterocyclic chemistry. Part 4. Metallation of 2-methoxypyridine: unusual behaviour of the new unimetal superbase BuLi–Me2N(CH2)2OLi (BuLi–LiDMAE)
Philippe Gros Yves Fort and Paul Caubère
pg 3071; DOI:
10.1039/a701914i
PDF
Regiospecific aromatic chlorination of alkyl phenyl ethers using sodium chlorite catalysed by manganese(III) acetylacetonate and moist alumina in dichloromethane
Masao Hirano Shigetaka Yakabe Hiroyuki Monobe James H. Clark and Takashi Morimoto
pg 3081; DOI:
10.1039/a701813d
PDF
Solvent-dependent ambident nucleophilicity of phenoxide ion towards nitroporphyrins: synthesis of 2-hydroxyaryl- and 2-aryloxy-5,10,15,20-tetraphenylporphyrins by displacement of a nitro group
Maxwell J. Crossley Lionel G. King and Janelle L. Simpson
pg 3087; DOI:
10.1039/a701673e
PDF
Model studies towards the synthesis of 4-azaerythrofuranosyladenines as analogues of the antiviral drug 2,3-dideoxyadenosine (ddA)1
Antonella Leggio Angelo Liguori Loredana Maiuolo Anna Napoli Antonio Procopio Carlo Siciliano and Giovanni Sindona
pg 3097; DOI:
10.1039/a701279i
PDF
Remarkable dependence of the regioselectivity of free radical additions to 3-cinnamoyloxazolidin-2-ones on the stability of the intermediate adduct-radical, electrophilicity of the adding radicals and the conditions for their generation
Vitali I. Tararov Nikolai Yu. Kuznetzov Vladimir I. Bakhmutov Nikolai S. Ikonnikov Yuri N. Bubnov Victor N. Khrustalev Tatiana F. Saveleva and Yuri N. Belokon
pg 3101; DOI:
10.1039/a701154g
PDF
Flash vacuum pyrolysis of stabilised phosphorus ylides. Part 11.1 Unexpected generation and rearrangement of acetyl benzotriazolyl carbene
R. Alan Aitken Ian M. Fairhurst Adrian Ford Paul E. Y. Milne Duncan W. Russell and Martin Whittaker
pg 3107; DOI:
10.1039/a604594d
PDF

Issue 21


Stereospecific and regioselective catalytic epoxidation of alkenes by a novel ruthenium(II) complex under aerobic conditions
Venkitasamy Kesavan and Srinivasan Chandrasekaran
pg 3115; DOI:
10.1039/a706729a
PDF
Conjugate Michael-additions with mixed diorganozincs
Philip Jones and Paul Knochel
pg 3117; DOI:
10.1039/a706637f
PDF
Alkynyl-pyridinium ylid complexes of tungsten(0) and chromium(0): synthesis and cascade insertion reactions
Blanca Martín-Vaca and Henri Rudler
pg 3119; DOI:
10.1039/a706584a
PDF
A new class of chiral macrocyclic polythiacrown systems and a caveat 1
Mikhail Grabarnik Israel Goldberg and Benzion Fuchs
pg 3123; DOI:
10.1039/a706580i
PDF
An efficient total synthesis of ()-laurene
Mukund G. Kulkarni and Dhananjay S. Pendharkar
pg 3127; DOI:
10.1039/a706510h
PDF
Triphenylphosphine promoted addition of dimethyl acetylenedicarboxylate to 1,2-benzoquinones: facile synthesis of novel -spirolactones
Vijay Nair J. Somarajan Nair A. U. Vinod and Nigam P. Rath
pg 3129; DOI:
10.1039/a706272i
PDF
Synthesis of the tetrahydroisoquinoline unit in the AB ring system of the novel antitumor-antibiotic tetrazomine
Viviana L. Ponzo and Teodoro S. Kaufman
pg 3131; DOI:
10.1039/a706070j
PDF
Selective mono- and bis-condensations of isophthalaldehyde derivative with 6-(o-aminoanilino)cyclodextrins
De-Qi Yuan Kahee Fujita Hidefumi Mizushima and Masatoshi Yamaguchi
pg 3135; DOI:
10.1039/a705506d
PDF
N-Methyl- and N-benzyl-4-amino[2.2]paracyclophanes as unique planar chiral auxiliaries
Andrew Pelter Huw Kidwell and Roger A. N. C. Crump
pg 3137; DOI:
10.1039/a705449a
PDF
Novel chemoselective and diastereoselective iron(III)-catalysed Michael reactions of 1,3-dicarbonyl compounds and enones
Jens Christoffers
pg 3141; DOI:
10.1039/a704873d
PDF
Hexaaza and octaaza macrocycles with 2-hydroxy-3,5-dimethylbenzyl pendant arms
S. W. Annie Bligh Nick Choi Evagoras G. Evagorou and Mary McPartlin
pg 3151; DOI:
10.1039/a704835a
PDF
Preparation and characterization of 6A-polyamine-mono-substituted -cyclodextrins
Bruce L. May Suzanna D. Kean Christopher J. Easton and Stephen F. Lincoln
pg 3157; DOI:
10.1039/a704467d
PDF
A new synthesis of pyrroles fused with polycyclic skeletons
Satoshi Ito Takashi Murashima and Noboru Ono
pg 3161; DOI:
10.1039/a704418f
PDF
Studies on pyrazines. Part 34.1 Synthetic approach, stability and tautomerism of 2,6-dihydroxypyrazines
Nobuhiro Sato Kaori Matsumoto Masayuki Takishima and Katsura Mochizuki
pg 3167; DOI:
10.1039/a704415a
PDF
New precursors for preparing organic conducting materials: synthesis of (R)-hydroxymethylbis(ethylenedithio)tetrathiafulvalene, and the ring expansion of a cyclic sulfate ester
Fabien Leurquin Turan Ozturk Melanie Pilkington and John D. Wallis
pg 3173; DOI:
10.1039/a704364c
PDF
Stereoselective synthesis of -O-fucosylated serine, threonine, tyrosine and saccharides
Hari Babu Mereyala Srinivas Reddy Gurrala and Rajendrakumar Reddy Gadikota
pg 3179; DOI:
10.1039/a704310d
PDF
Synthesis, structure and tropicity of an [11][13]fulvalene derivative
Gaku Yamamoto Yasuhiro Mazaki Ryoji Kobayashi Hiroyuki Higuchi and Jro Ojima
pg 3183; DOI:
10.1039/a704071g
PDF
Conversion of pyrroles into bi-1,2,5-thiadiazoles: a new route to biheterocycles
Xiao-Guang Duan and Charles W. Rees
pg 3189; DOI:
10.1039/a704065b
PDF
Regioselective biotransformations of dinitriles using Rhodococcus sp. AJ2701
Otto Meth-Cohn and Mei-Xiang Wang
pg 3197; DOI:
10.1039/a703904b
PDF
N-(Diphenylphosphinothioyl)hydroxylamine: preparation, characterisation and base-induced transposition of sulfur and oxygen atoms in its O-benzoyl derivative1
Martin J. P. Harger
pg 3205; DOI:
10.1039/a703695g
PDF
Desilylation of (Z)--dimethylphenylsilyl vinyl sulfides with fluoride ion:1 revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group to the sulfur
Bianca Flavia Bonini Mauro Comes Franchini Mariafrancesca Fochi Germana Mazzanti and Alfredo Ricci
pg 3211; DOI:
10.1039/a703662k
PDF
Efficient synthesis of (6R)-6-amino-1-methyl-4-(3-methylbenzyl)hexahydro-1H-1,4-diazepine from methyl (2R)- and (2S)-1-benzyloxycarbonylaziridine-2-carboxylates
Shiro Kato Hiroshi Harada and Toshiya Morie
pg 3219; DOI:
10.1039/a703661b
PDF
Preparation of optically active azophenolic crown ethers containing 1-phenylethane-1,2-diol and 2,4-dimethyl-3-oxapentane-1,5-diol as a chiral subunit: temperature-dependent enantiomer selectivity in the complexation with chiral amines1
Kazuko Ogasahara Keiji Hirose Yoshito Tobe and Koichiro Naemura
pg 3227; DOI:
10.1039/a703452k
PDF
Thermodynamically-controlled cyclisation and interconversion of oligocholates: metal ion templated living macrolactonisation
Paul A. Brady and Jeremy K. M. Sanders
pg 3237; DOI:
10.1039/a703390g
PDF
On the reaction of prop-2-enylidenetriphenylphosphorane derivatives. Novel synthesis of 4,9-methanocyclopentacycloundecene derivatives and their spectroscopic and chemical properties
Tohru Takayasu and Makoto Nitta
pg 3255; DOI:
10.1039/a703314a
PDF
Azabenzocycloheptenones. Part 20. Synthesis and utilisation of 4-amino-1,2,3,4-tetrahydro-1(1H)-benzazepines
Kevin I. Booker-Milburn Ian R. Dunkin Frances C. Kelly Abedawn I. Khalaf David A. Learmonth George R. Proctor and David I. C. Scopes
pg 3261; DOI:
10.1039/a703281a
PDF
Synthesis and hybridization properties of - and -oligodeoxynucleotides containing - and -1-(3-C-allyl-2-deoxy-D-erythro-pentofuranosyl)thymine and -1-[3-C-(3-aminopropyl)-2-deoxy-D-erythro-pentofuranosyl]thymine
Pia N. Jørgensen Ulrik S. Sørensen Henrik M. Pfundheller Carl E. Olsen and Jesper Wengel
pg 3275; DOI:
10.1039/a703173d
PDF
Synthesis of some novel -cyanoketene S,S-acetals and their use in heterocyclic synthesis
Galal H. Elgemeie Ahmed H. Elghandour Ali M. Elzanate and Sayed A. Ahmed
pg 3285; DOI:
10.1039/a702343j
PDF

Issue 22


Tetra-n-propylammonium perruthenate (TPAP)-catalysed oxidations of alcohols using molecular oxygen as a co-oxidant
Roman Lenz and Steven V. Ley
pg 3291; DOI:
10.1039/a707339i
PDF
Enantiospecific total synthesis of (+)-2-pupukeanone
Adusumilli Srikrishna and Thumkunta Jagadeeswar Reddy
pg 3293; DOI:
10.1039/a706321k
PDF
Stereocontrolled synthesis of ()--pinguisene and ()-pinguisenol
Adusumilli Srikrishna and Dange Vijaykumar
pg 3295; DOI:
10.1039/a705600a
PDF
Stereoselective epoxidation of electron poor dienes using poly(L-leucine)
Joanne V. Allen Michael W. Cappi Pierre D. Kary Stanley M. Roberts Natalie M. Williamson and L. Eduardo Wu
pg 3297; DOI:
10.1039/a706238i
PDF
1,5-Asymmetric induction of chirality: highly diastereoselective addition reactions of organoaluminium reagents into ketone groups in the side-chain of -allyltricarbonyliron lactone complexes
Steven V. Ley Liam R. Cox Graham Meek Karl-Heinz Metten Carmen Piqué and Julia M. Worrall
pg 3299; DOI:
10.1039/a704481j
PDF
1,5-Asymmetric induction of chirality: highly diastereoselective synthesis of homoallylic tertiary alcohols by the Lewis acid-mediated addition of allylstannanes into ketones in the side-chain of -allyltricarbonyliron lactone complexes
Steven V. Ley and Liam R. Cox
pg 3315; DOI:
10.1039/a704491g
PDF
1,5-Asymmetric induction of chirality: diastereoselective addition of organoaluminium reagents and allylstannanes into aldehyde groups in the side-chain of -allyltricarbonyliron lactone complexes
Steven V. Ley Svenja Burckhardt Liam R. Cox and Graham Meek
pg 3327; DOI:
10.1039/a704487i
PDF
Regioselective synthesis of bridged azabicyclic compounds using radical translocations/cyclisations of methyl 2-alkynyl-1-(o-iodobenzoyl)pyrrolidine-2-carboxylates: a formal total synthesis of ()-epibatidine
Masazumi Ikeda Yasuhiro Kugo Yukari Kondo Taro Yamazaki and Tatsunori Sato
pg 3339; DOI:
10.1039/a705226j
PDF
New routes to benzothiophenes, isothiazoles and 1,2,3-dithiazoles
Kumaraswamy Emayan Russell F. English Panayiotis A. Koutentis and Charles W. Rees
pg 3345; DOI:
10.1039/a704916a
PDF
Enantiospecific syntheses of (R)- and (S)-proline and some derivatives from D-glucono-1,5-lactone
Claudio Mazzini Letitia Sambri Henk Regeling Binne Zwanenburg and Gordon J. F. Chittenden
pg 3351; DOI:
10.1039/a704915c
PDF
Vinyl glycosides in oligosaccharide synthesis (part 4): glycosidase-catalysed preparation of substituted allyl glycosides
Robin R. Gibson Roger P. Dickinson and Geert-Jan Boons
pg 3357; DOI:
10.1039/a704703g
PDF
Stereoselective isomerisations of 4-(2,5-dimethoxyphenyl)-2,5-dimethyl-1,3-dioxolanes and their 2-chloro-5-methoxyphenyl analogues. Temperature-dependent diastereoselective formation of isochromanes
Robin G. F. Giles Rodney W. Rickards and Badra S. Senanayake
pg 3361; DOI:
10.1039/a704543c
PDF
Synthesis of oligomers related to nylon 6
Gerald M. Brooke Shahid Mohammed and Mark C. Whiting
pg 3371; DOI:
10.1039/a704457g
PDF
Synthesis of pyrido[2,3-c]acridines
Paul W. Groundwater and Munawar Ali Munawar
pg 3381; DOI:
10.1039/a704361i
PDF
Synthesis based on cyclohexadienes. Part 23.1 Total synthesis of 5-epi-pupukean-2-one
Krishna Kaliappan and G. S. R. Subba Rao
pg 3387; DOI:
10.1039/a704312k
PDF
Synthesis based on cyclohexadienes. Part 24.1 A new total synthesis of pupukean-2-one and a facile entry to copa and ylanga type sesquiterpene skeletons
Krishna Kaliappan and G. S. R. Subba Rao
pg 3393; DOI:
10.1039/a704314g
PDF
A study on the scope of the photochemical ring contraction of substituted 2-amino-3-cyano-4H-pyrans to cyclobutenes: crystal structure of 3-carbamoyl-3-cyano-1-ethoxycarbonyl-4-isopropyl-2-phenylcyclobutene
Diego Armesto Armando Albert Felix H. Cano Nazario Martín Ana Ramos Miriam Rodriguez Jose L. Segura and Carlos Seoane
pg 3401; DOI:
10.1039/a703938g
PDF
4,4-Dimethoxytrityl and 4,4,4-trimethoxytrityl as protecting groups for amino functions; selectivity for primary amino groups and application in 15N-labelling
Alistair P. Henderson Jane Riseborough Christine Bleasdale William Clegg Mark R. J. Elsegood and Bernard T. Golding
pg 3407; DOI:
10.1039/a703873i
PDF
Enantioselective synthesis of flavonoids. Part 3.1trans- and cis-Flavan-3-ol methyl ether acetates
Hendrik van Rensburg Pieter S. van Heerden and Daneel Ferreira
pg 3415; DOI:
10.1039/a703316h
PDF
Synthesis of 2-O,3-C-linked bicyclic nucleosides and bicyclic oligonucleotides
Poul Nielsen Henrik M. Pfundheller Carl Erik Olsen and Jesper Wengel
pg 3423; DOI:
10.1039/a703176i
PDF
Epimerization in acid degradation products of artemisinin
Shi-Man Hui Koon-Sin Ngo and Geoffrey D. Brown
pg 3435; DOI:
10.1039/a702714a
PDF
1,4-Dithiafulvene-substituted ferrocenes and their conversion into extended tetrathiafulvalene electron donors: synthetic, electrochemical and X-ray structural studies
Adrian J. Moore Martin R. Bryce Peter J. Skabara Andrei S. Batsanov Leonid M. Goldenberg and Judith A. K. Howard
pg 3443; DOI:
10.1039/a702554h
PDF
Switchable electron-rich biindolizine-based macrocycles: synthesis and redox properties
T. Kreher H. Sonnenschein B. Costisella and M. Schneider
pg 3451; DOI:
10.1039/a702433i
PDF
Studies on bis(2,35,6-di-O-isopropylidene-D-mannofuranosyl)amine and its protected and deprotected N-acyl derivatives – an approach to novel non-ionic surfactants
David F. Ewing John W. Goodby Sophie Guenais Philippe Letellier Grahame Mackenzie Isabelle Piastrelli and Daniel Plusquellec
pg 3459; DOI:
10.1039/a702346d
PDF
Thienothiophenes. Part 2.1 Synthesis, metallation and brominelithium exchange reactions of thieno[3,2-b]thiophene and its polybromo derivatives
Lance S. Fuller Brian Iddon and Kevin A. Smith
pg 3465; DOI:
10.1039/a701877k
PDF
Steric and electronic effects on the Weiss reaction. Isolation of 11 adducts
Scott G. Van Ornum Jin Li Greg G. Kubiak and James M. Cook
pg 3471; DOI:
10.1039/a701232b
PDF
The X-ray crystal structure, conformation and preparation of anti-3,3,6,6-tetramethylthiepane-4,5-diol: stereochemistry of reduction of a heterocyclic -hydroxy ketone
Neil Feeder Michael J. Ginnelly Ray V. H. Jones Susan OSullivan Stuart Warren and Paul Wyatt
pg 3479; DOI:
10.1039/a605572i
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Issue 23


Synthesis of pyridazine fatty ester derivatives in water: a sonochemical approach
Marcel S. F. Lie Ken Jie and Prabhavathi Kalluri
pg 3485; DOI:
10.1039/a705117d
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Expedient synthesis of lactone analogues of formestane as new potential aromatase inhibitors
Elisiário J. Tavares da Silva Maria L. Sá e Melo André S. Campos Neves José A. Paixão L. C. R. Andrade Maria-José M. Almeida and M. M. R. Costa
pg 3487; DOI:
10.1039/a705601j
PDF
Oxidation of sulfides to sulfoxides with 3-aryl-2-tert-butyloxaziridines under high pressure
Masao Shimizu Isao Shibuya Yoichi Taguchi Satoshi Hamakawa Kunio Suzuki and Takashi Hayakawa
pg 3491; DOI:
10.1039/a705022d
PDF
Stereoselective synthesis of (S)-MPPG, (S)-MTPG and (S)-(+)-M4CPG from (R)-4-hydroxyphenylglycine
Dawei Ma and Hongqi Tian
pg 3493; DOI:
10.1039/a704704e
PDF
Solvent-dependent conformations of a cyclic tetrapeptide
Makoto Tamaki Seiji Komiya Mikihiro Yabu Eiji Watanabe Sadatoshi Akabori and Ichiro Muramatsu
pg 3497; DOI:
10.1039/a704476c
PDF
Improved procedure for Juli–Colonna asymmetric epoxidation of ,-unsaturated ketones: total synthesis of diltiazem and TaxolTM side-chain
Brian M. Adger James V. Barkley Sophie Bergeron Michael W. Cappi Benjamin E. Flowerdew Mark P. Jackson Ray McCague Thomas C. Nugent and Stanley M. Roberts
pg 3501; DOI:
10.1039/a704413e
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Synthesis of chiral -aminophosphine oxides via novel azaboretidinium bromide salts1
Brian L. Booth Nicholas J. Lawrence and Humayan S. Rashid
pg 3509; DOI:
10.1039/a703936k
PDF
Stereospecific synthesis of naturally-occurring 4-alkylideneglutamic acids, 4-alkylglutamates and 4-alkylprolines1
Claire M. Moody and Douglas W. Young
pg 3519; DOI:
10.1039/a703489j
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Control of stereochemistry in an intramolecular Diels–Alder reaction by the phenylsulfonyl group; an improved synthesis of pisiferol
Edward J. Bush and David W. Jones
pg 3531; DOI:
10.1039/a702761c
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On the reaction of azulen-2-ylmethylene(triphenyl)phosphorane. Convenient preparation of azuleno[1,2-f]- and azuleno[1,2-a]-azulenes and their properties
Tohru Takayasu and Makoto Nitta
pg 3537; DOI:
10.1039/a702716h
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An efficient synthesis of novel N-acetyl-3-alkanoyl and 3-dienoyl tetramic acids
Margarita Petroliagi and Olga Igglessi-Markopoulou
pg 3543; DOI:
10.1039/a702649h
PDF
Structural separation of biological activities of jasmonates and related compounds
Siegfried Blechert Christian Bockelmann Oliver Brümmer Martin Füßlein Heidrun Gundlach Georg Haider Swen Hölder Toni M. Kutchan Elmar W. Weiler and Meinhart H. Zenk
pg 3549; DOI:
10.1039/a702494k
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Reaction of lithioamino anions with -oxoketene dithioketals: an improved and a new general method for the synthesis of -oxoketene S,N- and N,N-ketals
Okram Mukherjee Singh Hiriyakkanavar Junjappa and Hiriyakkanavar Ila
pg 3561; DOI:
10.1039/a701435j
PDF
Application of PdII-catalysed oxidative cyclisation of hydroxy(vinyl)furan: synthesis of (5R)-diastereomer of (+)-goniofufurone
Hari Babu Mereyala Rajendrakumar Reddy Gadikota and Ravikumar Krishnan
pg 3567; DOI:
10.1039/a703905k
PDF

Issue 24


A high yield conversion of tetrathiafulvalene into bis(ethylenedithio)tetrathiafulvalene and derivatives
Ronald L. Meline and Ronald L. Elsenbaumer
pg 3575; DOI:
10.1039/a707814e
PDF
Efficient chemoenzymatic synthesis of (2S,3S)-3-hydroxyleucine mediated by immobilised penicillin G acylase
Nitin W. Fadnavis Mohd. Sharfuddin S. Kumara Vadivel and Uday T. Bhalerao
pg 3577; DOI:
10.1039/a707507c
PDF
Tandem Wittig–Diels–Alder reaction between sugar-derived phosphoranes and sugar aldehydes. An easy route to optically pure highly oxygenated decalins
Sawomir Jarosz
pg 3579; DOI:
10.1039/a707447f
PDF
Pyrolysis of 1-substituted pyrazoles and chloroform at 550C: formation of -carboline from 1-benzylpyrazoles
Inayat A. Bhatti Reginald E. Busby Murtedza bin Mohamed John Parrick and C. J. Granville Shaw
pg 3581; DOI:
10.1039/a705364i
PDF
Competitive reactivity of the aryl isothiocyanate dipolarophile at NC versus CS with nucleophilic 1,3-dipoles: a combined experimental and theoretical study. The reactions of substituted 1,2,3-triazolium-1-aminide 1,3-dipoles with aryl isothiocyanates: new tricyclic thiazolo[4,5-d][1,2,3]triazoles
Richard N. Butler Denise C. Grogan Peter D. McDonald and Luke A. Burke
pg 3587; DOI:
10.1039/a705233b
PDF
Reactions of the alkyl radical attached to the ring nitrogen of 2-phenylthio-indole, -benzimidazole and -uracil
Tomohiro Uetake Mayumi Nishikawa and Masaru Tada
pg 3591; DOI:
10.1039/a705139e
PDF
Aggregative activation in heterocyclic chemistry. Part 5. Lithiation of pyridine and quinoline with the complex base BuLiMe2N(CH2)2OLi (BuLiLiDMAE)
Philippe Gros Yves Fort and Paul Caubère
pg 3597; DOI:
10.1039/a705027e
PDF
Preparation of carbocyclic, phosphonate analogues of cyclic adenosine monophosphate (cAMP)
Jennifer M. L. Hillman and Stanley M. Roberts
pg 3601; DOI:
10.1039/a704961g
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Phosphorus(III) ligands with fluorous ponytails
Pravat Bhattacharyya David Gudmunsen Eric G. Hope Ray D. W. Kemmitt Danny R. Paige and Alison M. Stuart
pg 3609; DOI:
10.1039/a704872f
PDF
Radical-mediated cyclisation of -aryl--dicarbonyl compounds to tetrahydrobenzocyclohepten-6-ones, hexahydrobenzocycloocten-6-ones and naphthalen-2(1H)-ones
Joanne F. Jamie and Rodney W. Rickards
pg 3613; DOI:
10.1039/a704869f
PDF
Perfluorocarbon fluids as solvent replacements
Richard D. Chambers and Andrew R. Edwards
pg 3623; DOI:
10.1039/a704823h
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Deracemization of ()-2,3-disubstituted oxiranes via biocatalytic hydrolysis using bacterial epoxide hydrolases: kinetics of an enantioconvergent process
Wolfgang Kroutil Martin Mischitz and Kurt Faber
pg 3629; DOI:
10.1039/a704812b
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The synthesis of kermesic acid and isokermesic acid derivatives and of related dihydroxyanthraquinones
Stephen J. Bingham and John H. P. Tyman
pg 3637; DOI:
10.1039/a704317a
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Dirhodium(II)-catalysed intramolecular carbon–hydrogen insertion reaction of -diazo ketones: stereoselective synthesis of 2,3-cis-2-alkyl-5-oxo-3-silyloxycyclopentanecarboxylates
Takayuki Yakura Seiji Yamada Yuka Kunimune Akiharu Ueki and Masazumi Ikeda
pg 3643; DOI:
10.1039/a704102k
PDF
Intramolecular photocyclisation reactions of 5-tert-butyldimethylsilyloxymethyl-3-(3-formylpropyl)furan-2(5H)-one: formation of bicyclic and spirobicyclic lactones
David Brown Michael G. B. Drew and John Mann
pg 3651; DOI:
10.1039/a703745g
PDF
Syntheses and structures of 3-stannylcholest-5-ene species
Heather J. Buchanan Philip J. Cox Solange M. S. V. Doidge-Harrison R. Alan Howie Marcel Jaspars and James L. Wardell
pg 3657; DOI:
10.1039/a703596i
PDF
Neurosteroid analogues. Part 5.1 Enantiomers of neuroactive steroids and benz[e]indenes: total synthesis, electrophysiological effects on GABAA receptor function and anesthetic actions in tadpoles
Yuefei Hu Lisa L. Wittmer Melissa Kalkbrenner Alex S. Evers Charles F. Zorumski and Douglas F. Covey
pg 3665; DOI:
10.1039/a703212i
PDF
Studies in sulfur heterocycles. Part 12.1 Use of 5,6-dihydrobenzo[b]thiophen-7(4H)-one in the synthesis of condensed sulfur heterocycles
Subhendu Sekhar Samanta Sukhen Chandra Ghosh and Asish De
pg 3673; DOI:
10.1039/a702317k
PDF
An unusual carbon–carbon bond scission reaction with molecular oxygen under mild conditions; formation of piperidines from 1-azabicyclo[2.2.2]octanes
Timothy Norris Dinos Santafianos and Jon Bordner
pg 3679; DOI:
10.1039/a701223c
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